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Removal of phthalates from aqueous solution by semiconductor photocatalysis: A review.
Journal of Hazardous Materials ( IF 13.6 ) Pub Date : 2020-07-12 , DOI: 10.1016/j.jhazmat.2020.123461
Xinzhu Pang 1 , Nathan Skillen 1 , Nimal Gunaratne 1 , David W Rooney 1 , Peter K J Robertson 1
Affiliation  

While phthalate esters are commonly used as plasticizers to improve the flexibility and workability of polymeric materials, their presence and detection in various environments has become a significant concern. Phthalate esters are known to have endocrine-disrupting effects, which affects reproductive health and physical development. As a result, there is now increased focus and urgency to develop effective and energy efficient technologies capable of removing these harmful compounds from the environment. This review explores the use of semiconductor photocatalysis as an efficient and promising solution towards achieving removal and degradation of phthalate esters. A comprehensive review of photocatalysts reported in the literature demonstrates the range of materials including commercial TiO2, solar activated catalysts and composite materials capable of enhancing adsorption and degradation. The degradation pathways and kinetics are also considered to provide the reader with an insight into the photocatalytic mechanism of removal. In addition, through the use of two key platforms (the technology readiness level scale and electrical energy per order), the crucial parameters associated with advancing photocatalysis for phthalate ester removal are discussed. These include enhanced surface interaction, catalyst platform development, improved light delivery systems and overall system energy requirements with a view towards pilot scale and industrial deployment.



中文翻译:

半导体光催化从水溶液中去除邻苯二甲酸盐的综述。

尽管邻苯二甲酸酯通常用作增塑剂以改善聚合物材料的柔韧性和可加工性,但它们在各种环境中的存在和检测已成为人们关注的重要问题。已知邻苯二甲酸酯具有破坏内分泌的作用,会影响生殖健康和身体发育。结果,现在越来越关注和迫切需要开发能够从环境中去除这些有害化合物的有效和节能技术。这篇综述探讨了将半导体光催化用作实现邻苯二甲酸酯的去除和降解的有效且有前途的解决方案。对文献中报道的光催化剂的全面综述显示了包括商用TiO 2在内的各种材料,能够增强吸附和降解的太阳能活化催化剂和复合材料。降解途径和动力学也被认为为读者提供了对光催化去除机理的认识。此外,通过使用两个关键平台(技术准备水平规模和每订单电能),讨论了与推进光催化去除邻苯二甲酸酯有关的关键参数。这些包括增强的表面相互作用,催化剂平台的开发,改进的光传输系统和整个系统的能源需求,以实现中试规模和工业部署。

更新日期:2020-07-18
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