Towards high-performance heterogeneous palladium nanoparticle catalysts for sustainable liquid-phase reactions,Reaction Chemistry & Engineering

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Towards high-performance heterogeneous palladium nanoparticle catalysts for sustainable liquid-phase reactions
Reaction Chemistry & Engineering ( IF 3.4 ) Pub Date : 2020-07-09 , DOI: 10.1039/d0re00197j
Beau Van Vaerenbergh _{1,

2,

3,

4,

5} , Jeroen Lauwaert _{1,

2,

3,

4,

5} , Pieter Vermeir _{1,

6,

7,

8,

9} , Joris W. Thybaut _{1,

2,

3,

4,

10} , Jeriffa De Clercq _{1,

2,

3,

4,

5}

Affiliation

High-performance supported palladium nanoparticle (Pd-NP) catalysts help to address the growing demand for ‘green’ chemical production processes. At present, literature information on how the NP characteristics, NP–support and support–reactant/product interactions affect the catalytic performance, is scattered. As a result, the present review aims to bring together and critically analyze the relevant literature reports on the catalytic performance of supported Pd-NP catalysts in various liquid-phase reactions such as (de-)hydrogenation, alcohol (electro-)oxidation and cross-coupling reactions. The five main NP support classes, i.e., metal oxides, zeolites, carbon structures, polymers and ordered porous materials, are discussed in detail. A thorough understanding about the catalytic behaviour of supported Pd-NP catalysts via the NP characteristics, NP–support and support–reactant/product interactions give useful insights to optimize current or even create novel NP catalysts for a specific liquid-phase reaction.

中文翻译：

迈向高性能多相钯纳米颗粒催化剂，实现可持续的液相反应

高性能负载型钯纳米颗粒（Pd-NP）催化剂有助于满足对“绿色”化学生产工艺不断增长的需求。目前，有关NP特性，NP-载体和载体-反应物/产物相互作用如何影响催化性能的文献信息很少。因此，本综述旨在汇集并严格分析有关负载的Pd-NP催化剂在各种液相反应（如（脱）加氢，醇（电）氧化和交联）中的催化性能的相关文献报道。 -偶联反应。NP的五个主要支持类别，即详细讨论了金属氧化物，沸石，碳结构，聚合物和有序多孔材料。通过NP特性，NP-载体和载体-反应物/产物的相互作用，对负载型Pd-NP催化剂的催化行为有透彻的了解，为优化电流甚至为特定的液相反应创建新型NP催化剂提供了有用的见识。

更新日期：2020-08-25

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