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Coceth sulfate characterization by electrospray ionization tandem mass spectrometry.
Rapid Communications in Mass Spectrometry ( IF 1.8 ) Pub Date : 2020-07-10 , DOI: 10.1002/rcm.8884
Alberto Onzo 1 , Maria A Acquavia 1, 2 , Tommaso R I Cataldi 3 , Mattia Ligonzo 1 , Donatella Coviello 1 , Raffaella Pascale 1 , Giuseppe Martelli 1 , Marcella Bondoni 2 , Laura Scrano 4 , Giuliana Bianco 1
Affiliation  

The anionic surfactants, among which are alkyl ether sulfates (AESs), are the most used class of surfactants in cleansing applications. The negatively charged head group of AESs is a sulfate moiety linked with a variable number of ethylene oxide units, i.e. a polyethylene glycol chain. The hydrophobic part of an AES is constituted by a linear alkyl chain of carbon atoms, generally obtained from natural fatty acids. Coconut oil fatty acids, including the sodium salts of coceth sulfate (CES) with chemical formula CxHy (OCH2CH2)n OSO3Na, are widely used as feedstock for AESs synthesis. CES is added to many cleaning products and detergents defined as non‐aggressive. Currently, no detailed structural information concerning the alkyl chain length x and, more importantly, the degree of ethoxylation n has been reported.

中文翻译:

通过电喷雾电离串联质谱法表征硫酸椰子胶。

阴离子表面活性剂是烷基醚硫酸盐(AES),是清洁应用中使用最广泛的一类表面活性剂。AES的带负电荷的头基是与可变数目的环氧乙烷单元(即聚乙二醇链)连接的硫酸盐部分。AES的疏水部分由碳原子的线性烷基链组成,通常从天然脂肪酸获得。椰子油脂肪酸,包括化学式为C x H y(OCH 2 CH 2n OSO 3的硫酸椰子二钠(CES)的钠盐Na,被广泛用作AES合成的原料。CES被添加到许多定义为非腐蚀性的清洁产品和洗涤剂中。目前,没有关于烷基链长x,更重要的是,乙氧基化度n的详细结构信息的报道。
更新日期:2020-08-11
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