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Comparison of structural, physical and optical properties of Na2O-B2O3 and Li2O-B2O3 glasses to find an advantageous host for CeO2 based optical and photonic applications
Journal of Non-Crystalline Solids ( IF 3.2 ) Pub Date : 2020-07-10 , DOI: 10.1016/j.jnoncrysol.2020.120268
Gurinder Pal Singh , Joga Singh , Parvinder Kaur , Simranpreet Kaur , Deepawali Arora , Ravneet Kaur , D.P. Singh

This study focuses on alkali oxide (lithium and sodium) glasses with an aim to explore suitable host for cerium ions which will enhance the optical properties like UV blocking efficiency. Conventional melt quench method was employed for making these glasses. FTIR results show conversion of BO3 to BO4 units and development of CeO4 groups with addition of CeO2. The increase in density values (2.10 to 2.67 g/cm3 for sodium glasses and 2.04 to 2.75 g/cm3 for Lithium glasses) and decrease in band gap values (3.16 to 2.40 eV for sodium glasses and 3.28 to 2.08 eV for Lithium glasses) in both glass systems confirm the modifier role of CeO2. Hardness of lithium-based glasses (1366.91 Kg/mm2) at 4 mol% of CeO2 is higher than the glasses containing sodium (1007.21 Kg/mm2). The obtained values of refractive index and transmittance show better suitability of CeO2 incorporated lithium glasses in some optical applications.



中文翻译:

比较Na 2 O-B 2 O 3和Li 2 O-B 2 O 3玻璃的结构,物理和光学性质,以找到基于CeO 2的光学和光子应用的有利基质

这项研究集中在碱金属氧化物(锂和钠)玻璃上,目的是探索适合铈离子的基质,以增强光学特性,例如紫外线阻隔效率。使用常规的熔体淬火方法来制造这些玻璃。傅立叶红外光谱(FTIR)结果表明,加入CeO 2后BO 3转变为BO 4单元并形成CeO 4基。密度值的增加(钠玻璃为2.10至2.67 g / cm 3,锂玻璃为2.04至2.75 g / cm 3)和带隙值的减小(钠玻璃为3.16至2.40 eV,锂玻璃为3.28至2.08 eV )在两种玻璃体系中均证实了CeO 2的改性剂作用。CeO 2为4摩尔%时,锂基玻璃(1366.91 Kg / mm 2)的硬度高于含钠的玻璃(1007.21 Kg / mm 2)。所获得的折射率和透射率值表明在某些光学应用中,掺入CeO 2的锂玻璃具有更好的适用性。

更新日期:2020-07-10
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