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Solvation enthalpy of selected glymes in the mixtures of N,N-dimethylformamide with propan-1-ol or methanol at 298.15 K. The solvent contribution to the solvation enthalpy of glymes
Journal of Molecular Liquids ( IF 5.3 ) Pub Date : 2020-07-10 , DOI: 10.1016/j.molliq.2020.113733
Małgorzata Jóźwiak , Katarzyna Łudzik , Maria Cokot , Andrzej Jóźwiak , Arkadiusz Kłys

The enthalpies of solution of monoglyme, diglyme, triglyme, tetraglyme, pentaglyme and hexaglyme in N,N-dimethylforamide+propan-1-ol mixtures have been measured at 298.15 K. The preferential solvation process of glymes molecules in the mixtures of N,N-dimethylformamide with methanol or propan-1-ol has been discussed. Then the contribution of DMF, PrOH, and MeOH to the solvation enthalpy of group (–CH2– and –O–) of glymes has been calculated. On the basis of the obtained data, the effect of the structural and energetic properties of the N,N-dimethylforamide+propan-1-ol mixtures on the solution enthalpy of glymes in this mixtures has been analyzed.



中文翻译:

NN-二甲基甲酰胺与丙-1-醇或甲醇的混合物在298.15 K下的溶剂焓。溶剂对溶剂的溶剂焓的贡献。

的单甘醇二甲醚,二甘醇二甲醚,三甘醇二甲醚,四甘醇二甲醚,pentaglyme的溶液和hexaglyme在焓ÑÑ -dimethylforamide +丙-1-醇的混合物已经在298.15 K.在的混合物甘醇二甲醚分子的优先溶剂化过程已经测量ÑÑ已经讨论了将二甲基甲酰胺与甲醇或丙-1-醇一起使用。然后,计算了DMF,PrOH和MeOH对甘醇二甲酸酯类(–CH 2 –和–O–)的溶剂化焓的贡献。基于所获得的数据,已经分析了NN-二甲基甲酰胺+丙-1-醇混合物的结构和能量性质对该混合物中甘氨酸的溶液焓的影响。

更新日期:2020-07-10
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