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Promotion of the performance of Cu-SSZ-13 for selective catalytic reduction of NOx by ammonia in the presence of SO2 during high temperature hydrothermal aging
Journal of Catalysis ( IF 6.5 ) Pub Date : 2020-07-10 , DOI: 10.1016/j.jcat.2020.06.041
Xin Yong , Cuijuan Zhang , Miao Wei , Pingping Xie , Yongdan Li

The influence of SO2 presence during high temperature hydrothermal aging (600, 700, and 800 °C) on the performance of Cu-SSZ-13 prepared by the conventional ion-exchange method for selective catalytic reduction of NOx by NH3 (NH3-SCR) was studied. The high-temperature activity of Cu-SSZ-13 is obviously enhanced by the SO2 presence for the 700 and 800 °C-aged samples and is not hampered for the 600 °C-aged sample. The presence of SO2 during hydrothermal aging has no influence on the framework Al. The interaction of Cu2+ with SO2 results in the formation of ZCuHSO4, which helps suppress the aggregation of Cu2+ into CuO and maintain more isolated Cu2+, leading to higher activity at high temperatures. The low Cu content yields higher relative population of Cu2+ species at more stable sites. The low-temperature (≤ 350 °C) activity is slightly lowered for the 600 and 700 °C-aged samples.



中文翻译:

的Cu-SSZ-13的性能用于选择性催化还原NO的促进X在SO的存在下,通过氨2高温水热老化期间

SO的影响2存在高温水热老化过程中对Cu-SSZ-13由对NO的选择性催化还原的常规离子交换法制备的性能(600,700,和800℃)X由NH 3(NH研究了3- SCR)。在700和800°C时效的样品中,SO 2的存在明显增强了Cu-SSZ-13的高温活性,而在600°C时效的样品中,则不受阻碍。水热老化过程中SO 2的存在对骨架Al没有影响。Cu 2+与SO 2的相互作用导致ZCuHSO 4的形成,这有助于抑制Cu的聚集2+转化为CuO并保持更多的孤立Cu 2+,从而在高温下具有更高的活性。低的Cu含量在更稳定的位点产生较高的Cu 2+物种相对种群。600和700°C时效样品的低温(≤350°C)活性略有降低。

更新日期:2020-07-10
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