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LaMnO3-La2CuO4 two-phase synergistic system with broad active window in NOx efficient reduction
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-07-09 , DOI: 10.1016/j.mcat.2020.111111
Yaohui Wu , Danyang Li , Jinkai Lu , Shangzhi Xie , Lihui Dong , Minguang Fan , Bin Li

The phase composition was tuned to discuss the intergrowth and coexistence effect for LaCu0.5Mn0.5O3 catalysts in NOx reduction. The two-phase system consisting of LaMnO3 and La2CuO4 had been thoroughly studied. Different phases in this two-phase system play the key role in NOx reduction at different temperatures, thereby maintaining excellent catalytic performance with broad active window from 300 to 1000 °C. In addition, this two-phase system was the first catalytic system to perform well in all of the following aspects, with decent practicability, superior long-term catalytic ability, excellent cyclic catalytic ability, reliable water and sulfur resistance, low toxicity, low cost, high reserves, and strong stability in high temperature range. This two-phase system had great value in practical applications. Furthermore, by the results of in situ DRIFTS and quasi-in situ XRD and XPS, the reaction mechanism was tentatively described in NOx reduction.



中文翻译:

的LaMnO 3 -La 2的CuO 4的两相,在NO宽活动窗口协同系统X有效的还原

相组合物调谐到讨论LACU共生和共存效果0.5的Mn 0.5 ø 3中的NO的催化剂X还原。对由LaMnO 3和La 2 CuO 4组成的两相系统进行了深入研究。此两相系统中的不同相在NO x中起关键作用在不同温度下还原,从而在300至1000°C的宽活性窗口范围内保持出色的催化性能。此外,该两相系统是在以下所有方面均表现良好的首个催化系统,具有良好的实用性,优异的长期催化能力,出色的循环催化能力,可靠的耐水和硫性,低毒性,低成本,高储量和在高温范围内的强稳定性。该两阶段系统在实际应用中具有很大的价值。此外,通过原位DRIFTS和准原位XRD和XPS的结果,在NO x还原中初步描述了反应机理。

更新日期:2020-07-09
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