Glass-ceramics with cubic BaTiO₃ as a major and hexagonal BaTi_1-xFe_xO_3-δ as a second phase were prepared by crystallization at 560°C in a glass with the composition 20.1Na₂O/23TiO₂/23.1BaO/3Al₂O₃/7.6B₂O₃/17.4SiO₂/5.8Fe₂O₃. X-ray photoelectron spectroscopy revealed presence of Ti⁴⁺ and Fe³⁺ ions in tetrahedral and octahedral coordination. Ba²⁺ occurs in different environments depending on the thermal history of the samples. The numbers of bridging and non-bridging oxygens vary with the crystallization time. Electron paramagnetic resonance spectroscopy showed four types of Fe³⁺ ions that are non-uniformly distributed in the samples: Fe³⁺ ions in magnetic domains, isolated Fe³⁺ in a rhombic crystal field, magnetically coupled Fe³⁺ ions in BaTiO₃ and Fe³⁺ ions located in a crystalline phase. The ratio between the described types of Fe³⁺ ions depends on the annealing time. Mössbauer spectroscopy detected Fe³⁺ tetrahedral and octahedral coordinated in the glass. Fe³⁺ was incorporated in distorted octahedral and pentahedral coordination in the Ti⁴⁺ sites of hexagonal BaTiO₃ crystals, the electroneutrality being preserved by the occurrence of oxygen vacancies. Vibrating sample magnetometer measurements were used to determine ferromagnetic properties in samples crystallized for times ≥ 3 h. Maximum magnetization of 0.8 emu/g and a coercive force of 25 Oe were determined for the sample crystallized for 3 h at 560°C.

在560 _℃结晶，制备了以立方BaTiO ₃为主要成分和六方BaTi _1-x Fe _x O3 _-δ为第二相的玻璃陶瓷。组成为20.1Na ₂ O / 23TiO ₂ /23.1BaO/3Al ₂ O ₃ /7.6B ₂ O ₃ /17.4SiO ₂ /5.8Fe ₂ O ₃的玻璃中的℃ 。X射线光电子能谱显示四面体和八面体配位存在Ti ⁴⁺和Fe ³⁺离子。根据样品的热历史，Ba ²⁺会在不同的环境中发生。桥接氧和非桥接氧的数目随结晶时间而变化。电子顺磁共振光谱显示出四种类型的Fe ³⁺样品中分布不均匀的离子：磁畴中的Fe ³⁺离子，菱形晶场中的孤立Fe ^{3 +}，BaTiO _3中的磁耦合Fe ³⁺离子和位于晶相中的Fe ³⁺离子。所述类型的Fe ³⁺离子之间的比例取决于退火时间。穆斯堡尔光谱法检测到玻璃中配位的Fe ³⁺四面体和八面体。铁³⁺在八面体和五面体协调纳入钛⁴⁺六方钛酸钡的网站₃晶体，电子中性被氧空位的出现所保留。振动样品磁力计测量用于确定结晶≥3小时的样品中的铁磁性能。在560℃结晶3小时的样品的最大磁化强度为0.8 emu / g，矫顽力为25 Oe℃。