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Decoration of mesoporous carbon electrodes with tin oxide to boost their supercapacitive performance
New Journal of Chemistry ( IF 3.3 ) Pub Date : 2020-07-08 , DOI: 10.1039/d0nj02585b
Hang T. T. Le 1, 2, 3, 4 , Duc Tung Ngo 4, 5, 6, 7 , Viet-Anh-Dung Dang 1, 2, 3, 4 , Thuy T. B. Hoang 1, 2, 3, 4 , Chan-Jin Park 8, 9, 10, 11
Affiliation  

Mesoporous carbon (N-CMK3) decorated with different amounts of SnO2 nanoparticles was prepared in a controllable manner by using an incipient wetness impregnation technique, followed by a chemical reduction process, for application as a supercapacitor. The results of the analysis demonstrated that the surface area and pore volume of N-CMK3 decorated with SnO2 continued to decrease after impregnation with increasing amounts of SnO2. The results of the electrochemical measurement proved that decoration of N-CMK3 with a suitable amount of SnO2 enhanced the specific capacitance of the electrodes. Among the SnO2@N-CMK3 (SNC) samples under investigation, 15-SNC with 15 wt% SnO2 delivered outstanding electrochemical performance with respect to specific capacitance and cycling stability. At a scan rate of 5 mV s−1, 15-SNC exhibited superspecific capacitance up to 344 F g−1 and long-term cyclability at a scan rate of 50 mV s−1 with 92.4% retention of its initial specific capacitance of 161 F g−1 after 5000 cycles.

中文翻译:

用氧化锡装饰中孔碳电极以增强其超电容性能

通过使用初期湿润浸渍技术,然后通过化学还原工艺,以可控方式制备装饰有不同数量SnO 2纳米粒子的介孔碳(N-CMK3),以用作超级电容器。分析的结果表明,装饰具有SnO的N- CMK3的表面积和孔体积2继续浸渍后降低随的SnO量2。电化学测量的结果证明,用适量的SnO 2修饰N-CMK3可以提高电极的比电容。在所研究的SnO 2 @ N-CMK3(SNC)样品中,含15 wt%SnO 2的15-SNC在比电容和循环稳定性方面具有出色的电化学性能。在5 mV s -1的扫描速率下,15-SNC表现出高达344 F g -1的超比电容,在50 mV s -1的扫描速率下具有长期可循环性,其初始比电容161保持92.4%5000次循环后的F g -1
更新日期:2020-07-27
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