Stimuli-responsive structural changes in metal-organic frameworks.,Chemical Communications

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Stimuli-responsive structural changes in metal-organic frameworks.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-07-08 , DOI: 10.1039/d0cc03197f
Zhanning Liu ₁ , Lu Zhang ₁ , Daofeng Sun ₁

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In the past decades, metal–organic frameworks (MOFs) have attracted considerable interest not only for their intrinsic aesthetic appeal but also their wide potential applications. The most distinctive feature of MOFs is their flexibility, which makes them exhibit a much larger magnitude of responses toward external stimuli than traditional materials. In addition, the stimuli usually have a huge impact on the MOFs’ performances. A fundamental understanding of the structure evolution process under external stimuli is critical to reveal the structure–property relationships in MOFs. In this feature article, we tried to summarize how the crystal structure changes toward external stimuli, such as guest insertion, temperature, pressure, electric field, and light.

中文翻译：

金属有机骨架中的刺激响应性结构变化。

在过去的几十年中，金属有机框架（MOF）不仅因为其内在的美学吸引力，而且还因为其广泛的潜在应用而引起了人们的极大兴趣。MOF最显着的特点是它们的灵活性，这使得它们对外部刺激的反应程度要比传统材料大得多。此外，刺激通常会对财政部的业绩产生巨大影响。对外部刺激下结构演化过程的基本理解对于揭示MOF中的结构与属性之间的关系至关重要。在这篇专题文章中，我们试图总结出晶体结构如何朝着外部刺激（如宾客插入，温度，压力，电场和光）变化。

更新日期：2020-08-19

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