当前位置: X-MOL 学术Mol. Catal. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Facile preparation of hollow MnOx-CeO2 composites with low Ce content and their catalytic performance in NO oxidation
Molecular Catalysis ( IF 3.9 ) Pub Date : 2020-07-08 , DOI: 10.1016/j.mcat.2020.111107
Qingnan Meng , Juanni Cui , Kai Wang , Yufei Tang , Kang Zhao , Li Huang

The Mn-Ce mixed oxides are frequently used for catalytic oxidation of NO. However, to achieve better performance, a large amount of Ce element is usually engaged in the preparation, in spite of its low abundance and high cost. Herein, a facile sovothermal method was presented to prepare hollow MnOx-CeO2 composites. The structural and physiochemical properties of the products were carefully investigated and their catalytic performance was evaluated. The most active sample possesses a bulk Mn/(Mn + Ce) ratio of 74.5 %, which shows a maximum NO conversion of 90.6 % at 270 °C (GHSV = 120,000 h−1). It is believed that the superior catalytic activity is largely due to the enrichment of Ce element and the high content of Mn4+ species on the surface, while the porous structure is also beneficial.



中文翻译:

低铈含量的中空MnOx-CeO 2复合材料的制备及其在NO氧化中的催化性能

Mn-Ce混合氧化物常用于NO的催化氧化。然而,为了获得更好的性能,尽管其Cb元素含量低且成本高,但是通常会在制备中使用大量的Ce元素。在此,提出了一种简便的声热方法来制备中空MnOx-CeO 2复合材料。仔细研究了产物的结构和物理化学性质,并评估了它们的催化性能。活性最高的样品的总Mn /(Mn + Ce)比为74.5%,在270°C(GHSV = 120,000 h -1)时显示最大NO转化率为90.6%。可以认为,优异的催化活性主要归因于Ce元素的富集和Mn 4+的高含量 物质在表面上,而多孔结构也是有益的。

更新日期:2020-07-08
down
wechat
bug