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Chromium based metal–organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2020-07-07 , DOI: 10.1039/d0nj01931c
Nurdan Caner 1, 2, 3, 4, 5 , Mehmet Yurderi 1, 2, 3, 4, 5 , Ahmet Bulut 1, 2, 3, 4, 5 , Gulsah Saydan Kanberoglu 1, 2, 3, 4, 5 , Murat Kaya 5, 6, 7, 8 , Mehmet Zahmakiran 1, 2, 3, 4, 5
Affiliation  

Palladium nanoparticles stabilized by an MIL-101 metal–organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H2 generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min−1) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.

中文翻译:

铬基金属有机框架MIL-101装饰的钯纳米颗粒用于氨硼烷的甲醇分解

通过一种新型的合成方法合成了由MIL-101金属-有机骨架(Pd @ MIL-101)稳定的钯纳米粒子。在室温下,Pd @ MIL-101催化剂有助于氨硼烷的甲醇分解产生H 2,并具有创纪录的催化活性(TOF = 1080 min -1)。此外,Pd @ MIL-101的出色稳定性使其成为这种催化转化中可重复使用的非均相催化剂。
更新日期:2020-07-27
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