Chromium based metal–organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane,New Journal of Chemistry

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Chromium based metal–organic framework MIL-101 decorated palladium nanoparticles for the methanolysis of ammonia-borane
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2020-07-07 , DOI: 10.1039/d0nj01931c
Nurdan Caner _{1,

2,

3,

4,

5} , Mehmet Yurderi _{1,

2,

3,

4,

5} , Ahmet Bulut _{1,

2,

3,

4,

5} , Gulsah Saydan Kanberoglu _{1,

2,

3,

4,

5} , Murat Kaya _{5,

6,

7,

8} , Mehmet Zahmakiran _{1,

2,

3,

4,

5}

Affiliation

Palladium nanoparticles stabilized by an MIL-101 metal–organic framework (Pd@MIL-101) are synthesized by a novel synthesis approach. A Pd@MIL-101 catalyst facilitates H₂ generation from the methanolysis of ammonia-borane with record catalytic activity (TOF = 1080 min⁻¹) at room temperature. Moreover, the exceptional stability of Pd@MIL-101 makes it a reusable heterogeneous catalyst in this catalytic transformation.

中文翻译：

铬基金属有机框架MIL-101装饰的钯纳米颗粒用于氨硼烷的甲醇分解

通过一种新型的合成方法合成了由MIL-101金属-有机骨架（Pd @ MIL-101）稳定的钯纳米粒子。在室温下，Pd @ MIL-101催化剂有助于氨硼烷的甲醇分解产生H ₂，并具有创纪录的催化活性（TOF = 1080 min ^-1）。此外，Pd @ MIL-101的出色稳定性使其成为这种催化转化中可重复使用的非均相催化剂。

更新日期：2020-07-27

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