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Structure and Properties of (CH3NH3)3Tl2Cl9: A Thallium-Based Hybrid Perovskite-Like Compound.
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-07-07 , DOI: 10.1021/acs.inorgchem.0c01321 Rodrigo Castillo 1 , Jonathan Cisterna 2 , Ivan Brito 2 , Sergio Conejeros 1 , Jaime Llanos 1
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-07-07 , DOI: 10.1021/acs.inorgchem.0c01321 Rodrigo Castillo 1 , Jonathan Cisterna 2 , Ivan Brito 2 , Sergio Conejeros 1 , Jaime Llanos 1
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The new compound (CH3NH3)3Tl2Cl9 was synthesized and fully characterized. X-ray photoelectron spectroscopy and Raman spectroscopy are consistent with the crystal structure solved by single-crystal X-ray diffraction. This compound is a semiconductor with a measured band gap of Eg = 2.91 eV. It is the first thallium-based hybrid perovskite and shows remarkably high stability to ambient conditions.
中文翻译：
（CH3NH3）3Tl2Cl9的结构和性质：T基杂化钙钛矿样化合物。
合成并充分表征了新的化合物（CH 3 NH 3）3 Tl 2 Cl 9。X射线光电子能谱和拉曼光谱与通过单晶X射线衍射解析的晶体结构一致。该化合物是带隙为E g = 2.91 eV的半导体。它是第一个基于hybrid的钙钛矿杂化材料，在环境条件下显示出很高的稳定性。
更新日期：2020-07-20
中文翻译：
（CH3NH3）3Tl2Cl9的结构和性质：T基杂化钙钛矿样化合物。
合成并充分表征了新的化合物（CH 3 NH 3）3 Tl 2 Cl 9。X射线光电子能谱和拉曼光谱与通过单晶X射线衍射解析的晶体结构一致。该化合物是带隙为E g = 2.91 eV的半导体。它是第一个基于hybrid的钙钛矿杂化材料，在环境条件下显示出很高的稳定性。
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