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Visible light assisted photocatalytic reduction of CO2 to methanol using Fe3O4@N-C/Cu2O nanostructure photocatalyst
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2020-07-07 , DOI: 10.1016/j.jphotochem.2020.112763
Siyavash Kazemi Movahed , Amir Najinasab , Roonak Nikbakht , Minoo Dabiri

Copper oxide (I) nanoparticles decorated on nitrogen-doped carbon (N-C) rod-shaped core-shell nanostructure have been successfully prepared. The nanostructures have been developed by the reduction of Cu2+ with ascorbic acid over Fe3O4@N-C rod-shaped core-shell nanostructure followed by aerobic oxidation of copper nanoparticles. Furthermore, the photocatalytic activity of Fe3O4@N-C/Cu2O nanostructure was evaluated in selective CO2 reduction and methanol was observed as the main product over Fe3O4@N-C/Cu2O. The photocatalytic activity of Fe3O4@N-C/Cu2O for CO2 reduction was found to be about four times higher than that of Fe3O4@Cu2O photocatalyst, which might be due to the enhancement of visible light absorption and facilitating the separation of photogenerated electron-hole pairs.



中文翻译:

Fe 3 O 4 @ N -C / Cu 2 O纳米结构光催化剂在可见光辅助下将CO 2光催化还原为甲醇

已成功制备了装饰有氮掺杂碳(N -C)棒状核-壳纳米结构的氧化铜(I)纳米粒子。通过在Fe 3 O 4 @ N -C棒状核壳纳米结构上用抗坏血酸还原Cu 2+,然后对铜纳米颗粒进行好氧氧化,从而开发出纳米结构。此外,通过选择性还原CO 2评估了Fe 3 O 4 @ N -C / Cu 2 O纳米结构的光催化活性,并观察到以甲醇为主要产物的Fe 3 O 4 @ N -C / Cu的光催化活性。2 O.铁的光催化活性3 ö 4 @ Ñ -C /铜2 O代表CO 2减少被发现是大约四倍比Fe更高3 ö 4 @Cu 2 ö光催化剂,这可能是由于增强可见光吸收并促进光生电子-空穴对的分离。

更新日期:2020-07-07
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