当前位置: X-MOL 学术Food Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Role of salt ions and molecular weights on the formation of Mesona chinensis polysaccharide-chitosan polyelectrolyte complex hydrogel.
Food Chemistry ( IF 8.8 ) Pub Date : 2020-07-06 , DOI: 10.1016/j.foodchem.2020.127493
Jun Yang 1 , Mingyue Shen 1 , Ting Wu 1 , Yu Luo 1 , Mingyu Li 1 , Huiliang Wen 2 , Jianhua Xie 1
Affiliation  

The effects of the addition of salt ions and molecular weights (Mw) of CH on Mesona chinensis polysaccharide (MCP)-chitosan (CH) hydrogel were investigated. Result indicated both low concentration of monovalent salt ions (Na+ and K+), divalent cations (Ca2+) and oxoanions (SO42−) could promote the gel properties of MCP-CH hydrogel. The Mw of CH has huge impact on the formation and properties of hydrogel. Combining the relationship between rheology and structural, monovalent salt ions such as Na+ and K+ affect gel formation and its properties by influencing electrostatic interaction and chain conformation. Both divalent cations (Ca2+) and oxoanions (SO42−) facilitated the formation of gel networks via electrostatic interaction, coordination bonds and hydrogen bonds. Moreover, Mw of CH influenced formation and texture of MCP-CH hydrogel via affecting the conformation of CH molecular chain. These findings will provide a few theoretical bases to understand the formation mechanism of MCP-CH hydrogel.



中文翻译:

盐离子和分子量对中型多糖-壳聚糖聚电解质复合水凝胶形成的作用。

在添加盐离子和分子量的(效果中号w)的CH的上凉粉羊草多糖(MCP) -脱乙酰壳聚糖(CH)的水凝胶进行了研究。结果表明,低浓度的一价盐离子(Na +和K +),二价阳离子(Ca 2+)和含氧阴离子(SO 4 2-)均可促进MCP-CH水凝胶的凝胶性能。CH的M w对水凝胶的形成和性质具有巨大影响。结合流变学与结构性单价盐离子(例如Na +和K +)之间的关系通过影响静电相互作用和链构象,影响凝胶的形成及其性质。二价阳离子(Ca 2+)和氧阴离子(SO 4 2-)都通过静电相互作用,配位键和氢键促进了凝胶网络的形成。此外,CH的M w通过影响CH分子链的构象影响MCP-CH水凝胶的形成和质地。这些发现将为理解MCP-CH水凝胶的形成机理提供一些理论基础。

更新日期:2020-07-10
down
wechat
bug