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Sonication induced transesterification of castor oil into biodiesel in the presence of MgO/CaO nanorods as a novel basic catalyst: Characterization and optimization
Chemical Engineering and Processing: Process Intensification ( IF 3.8 ) Pub Date : 2020-07-07 , DOI: 10.1016/j.cep.2020.108024
Mostafa R. Abukhadra , Aya S. Mohamed , Ahmed M. El-Sherbeeny , Ahmed Tawhid Ahmed Soliman , Abd Elatty E. Abd Elgawad

MgO/CaO nanorods (MgO/CaO NRs) were synthesized using a diatomite substrate under the microwave irradiation. The synthesized composite exhibits well-developed rod-like morphology with 112.8 m2/g BET surface area. The synthetic MgO/CaO NRs were evaluated as a potential catalyst in the transesterification of non-edible castor oil into biodiesel. The catalyst achieved stunning catalytic performance with biodiesel yield of 96.2 % within 70 min using 6 wt.,% of it as loading value after fixing the temperature at 70 °C and the ethanol-to-the used castor oil molar ratio at 15:1 by normal mixing. The sonication effect resulted in an enhancement in the yield to about 98.8 % after 60 min only and reduced the required ethanol, catalyst dosage and temperature. The characterization of the resulted castor oil-based biodiesel by the two mixing technique is of strong matching with the qualifications of EN 14214 as well as the ASTM D-6571 international standards of biodiesel.



中文翻译:

在作为新型基本催化剂的MgO / CaO纳米棒的存在下,超声诱导的蓖麻油酯交换成生物柴油:表征和优化

MgO / CaO纳米棒(MgO / CaO NRs)是在硅藻土的微波辐射下合成的。合成的复合材料具有112.8 m 2的发达的棒状形态/ g BET表面积。合成的MgO / CaO NRs被评估为非食用蓖麻油酯交换为生物柴油的潜在催化剂。将温度固定在70°C且乙醇与废蓖麻油的摩尔比固定为15:1后,该催化剂以70%的生物柴油收率达到了惊人的催化性能,生物柴油收率为96.2%,其中6 wt。%作为负载量。通过正常混合。仅在60分钟后,超声处理的结果将收率提高到约98.8%,并降低了所需的乙醇,催化剂的用量和温度。通过两种混合技术对所得的蓖麻油基生物柴油的表征与EN 14214的资格以及ASTM D-6571国际生物柴油标准高度匹配。

更新日期:2020-07-07
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