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Synthesis and photoluminescence characteristics of Dy incorporated MoO3 phosphor: Suppression concentration quenching.
Applied Radiation and Isotopes ( IF 1.6 ) Pub Date : 2020-07-07 , DOI: 10.1016/j.apradiso.2020.109321
M Ayvacikli 1 , Ümit H Kaynar 2 , Y Karabulut 3 , A Canimoglu 4 , M Bakr 5 , S Akca 6 , N Can 7
Affiliation  

A series of MoO3:Dy3+ phosphors have been synthesized via the gel-combustion method. The X-ray and photoluminescence (PL) emission spectra were employed to characterize the obtained phosphors. The prepared samples were characterized through XRD measurements and exhibited that Dy3+ ions can be successfully incorporated into the host material. The PL emission bands of Dy3+ doped MoO3 were observed at 486 nm, 574 nm and 666 nm which are assigned to the transitions of 4F9/2 → 6H15/2, 4F9/2 → 6H13/2 and 4F9/2 → 6H11/2, respectively. Concentration quenching were largely taken into consideration as one of the crucial aspects limiting the application range of phosphors in today's modern world. An abnormal thermal quenching dependence was reported when Dy3+ ions were incorporated into MoO3 host matrix. In order to understand the origin of this beneficial behaviour, energy transfer processes occurring via radiative and nonradiative mechanisms were investigated to elucidate this suppression of the concentration quenching.



中文翻译:

掺Dy的MoO3荧光粉的合成和光致发光特性:抑制浓度猝灭。

通过凝胶燃烧法合成了一系列的MoO 3:Dy 3+荧光粉。X射线和光致发光(PL)发射光谱用于表征获得的磷光体。通过XRD测量对制备的样品进行表征,结果表明Dy 3+离子可以成功地掺入主体材料中。Dy的组成PL发射带3+掺杂的MoO 3中在486处观察到的,574纳米和666纳米,它被分配给的过渡4 ˚F 9/2  →  6 ħ 15/24 ˚F 9/2  →  6 ħ 13 / 24 ˚F 9/2  →  6 ħ 11/2,分别。浓度淬灭是当今限制荧光粉应用范围的关键方面之一,已被广泛考虑。当将Dy 3+离子掺入MoO 3主体基质中时,报告了异常的热猝灭依赖性。为了了解这种有益行为的起源,研究了通过辐射和非辐射机制发生的能量转移过程,以阐明这种抑制浓度猝灭的方法。

更新日期:2020-07-07
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