Interaction of carbon monoxide with doped metal clusters,CrystEngComm

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Interaction of carbon monoxide with doped metal clusters
CrystEngComm ( IF 2.6 ) Pub Date : 2020-07-06 , DOI: 10.1039/d0ce00733a
Piero Ferrari _{1,

2,

3,

4,

5} , Guillaume Libeert _{1,

2,

3,

4,

5} , Nguyen Minh Tam _{6,

7,

8,

9} , Ewald Janssens _{1,

2,

3,

4,

5}

Affiliation

The interaction between carbon monoxide and metal-based catalysts is important in several reactions such as CO hydrogenation, CO oxidation, and CO₂ reduction. Consequently, CO adsorption on metal surfaces and nanoparticles largely has been investigated. Current understanding of the microscopic mechanism that governs the metal–CO binding has been enhanced by gas phase studies of well-defined small metal cluster model systems as a function of their size, charge state, and composition. In this highlight paper, key experimental and computational studies dealing with the interaction between CO and transition and coinage metal clusters are discussed, with particular emphasis on the influence of dopant atoms.

中文翻译：

一氧化碳与掺杂金属簇的相互作用

一氧化碳与金属基催化剂之间的相互作用在诸如CO加氢，CO氧化和CO ₂还原的若干反应中很重要。因此，已经大量研究了CO在金属表面和纳米颗粒上的吸附。通过对定义明确的小型金属簇模型系统进行气相研究，研究了其与金属-CO结合的微观机理，这是它们的大小，电荷状态和组成的函数。在这篇重点论文中，讨论了有关CO与过渡金属和造币金属簇之间相互作用的关键实验和计算研究，尤其着重于掺杂原子的影响。

更新日期：2020-07-27

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