Herein, the relation between the Arrhenius crossover (AC) behaviors in the structural relaxation and the electrical conductivity relaxation is explored in terms of the Bond Strength–Coordination Number Fluctuation (BSCNF) model developed by the authors. For the ionic glass‐forming liquids and solution examined, Ca₂K₃(NO₃)₇, Ca₂Rb₃(NO₃)₇, ZBLAN20 and (LiCl)_0.16(H₂O)_0.84, the electric conductivity at high temperature resembles the behavior of the high‐temperature structural relaxation. This mutual relationship suggests a similar origin of the AC behaviors for both, structural and electrical relaxation. The difference between them is reflected in the different temperatures that demarcate the AC behaviors. The implication of this difference to the occurrence of the high ionic conduction via the decoupling mechanism is discussed in terms of the BSCNF model and the fractional Stokes–Einstein law.

中文翻译：

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离子玻璃形成液中的Arrhenius交换现象和离子电导率

在本文中，作者根据开发的键强度-配位数波动（BSCNF）模型探讨了结构弛豫中的Arrhenius穿越（AC）行为与电导率弛豫之间的关系。对于所检查的离子玻璃形成液和溶液，Ca ₂ K ₃（NO ₃）₇，Ca ₂ Rb ₃（NO ₃）₇，ZBLAN20和（LiCl）_0.16（H ₂ O）_0.84，高温下的电导率类似于高温结构弛豫的行为。这种相互关系表明，在结构和电弛豫方面，交流行为的起因相似。它们之间的差异反映在划分AC行为的不同温度中。通过BSCNF模型和分数斯托克斯-爱因斯坦定律讨论了这种差异通过去耦机制对高离子传导的影响。