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Corrigendum: Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene.
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2020-07-06 , DOI: 10.1002/anie.202007100
Arseni Kostenko , Boris Tumanskii , Yuzuru Kobayashi , Masaaki Nakamoto , Akira Sekiguchi , Yitzhak Apeloig

In this Communication, the statement on page 10183, right column, “In one case, that of tetrakis(t‐butyl)cyclobutadiene, crystallographic X‐ray data measured at room temperature suggested a square geometry, and the authors argued that it has a triplet ground state.[8]”, is wrong and should be replaced by: “In one case, the possibility of a diradical reactivity was suggested, but no EPR studies supporting a triplet state were reported.[8]” The following sentence, “However, no spectroscopic support for this claim (e.g. EPR) was presented and the observed chemistry of this compound did not grant a conclusive evidence for the triplet state”, should be removed.



中文翻译:

更正:环丁二烯三重态双自由基状态的光谱观察。

在本来文中,第10183页右栏的声明:“在一种情况下,四(丁基)环丁二烯在室温下测得的结晶X射线数据表明其为方形几何形状,作者认为它具有三重态基态。[8]是错误的,应替换为:“在一种情况下,有人提出可能发生双基反应性,但没有报道支持三线态的EPR研究。[8] “以下句子:“但是,没有提出对此主张的光谱支持(例如EPR),并且观察到的该化合物的化学性质未提供有关三重态的确凿证据”。

更新日期:2020-07-06
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