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Manufacturing method of the heat-storable carbon fiber reinforced plastics with applying trans-1,4-polybutadiene by using cellulose nanofibers and electrodeposition solution
Journal of Energy Storage ( IF 8.9 ) Pub Date : 2020-07-06 , DOI: 10.1016/j.est.2020.101636
Kazuaki Katagiri , Tsuyoshi Totani , Takuya Isono , Ryohei Goto , Shimpei Yamaguchi , Sonomi Kawakita , Tomoatsu Ozaki , Hirosuke Sonomura , Sayaka Minami , Shinya Honda , Katsuhiko Sasaki

For the thermal management of electric devices, the application of phase change materials (PCMs) such as paraffin has been studied. However, as long as the PCM changes to liquid phase, a sealed structure is required, which is a constraint for weight reduction. Therefore, the authors have focused on trans-1,4-polybutadiene (TPBD), a semi-crystalline polymer that accumulates heat by crystal structure transition at 50~80 °C in the solid phase. However, the strength of TPBD is insufficient and thermal conductivity is not enough to dissipate the heat. In this study, a method to homogeneously apply TPBD to the surface of carbon fiber reinforced plastics (CFRP) was developed using cellulose nanofiber (CNF) and aqueous electrodeposition solution containing a polymer with epoxy group. The heat-storable CFRP was obtained, the maximum exoergic and endoergic heats of 30 J/g were confirmed, and its tensile strength was approximately 61% of CFRP without TPBD/CNF.



中文翻译:

纤维素纳米纤维和电沉积溶液涂覆反式1,4-聚丁二烯的热储存碳纤维增强塑料的制造方法

对于电子设备的热管理,已经研究了相变材料(PCM)(例如石蜡)的应用。然而,只要PCM变为液相,就需要密封结构,这是减轻重量的限制。因此,作者都集中在1,4-聚丁二烯(TPBD)是一种半结晶聚合物,通过固相在50〜80°C时的晶体结构转变而积聚热量。然而,TPBD的强度不足并且导热率不足以散发热量。在这项研究中,开发了一种使用纤维素纳米纤维(CNF)和含环氧基聚合物的水性电沉积溶液将TPBD均匀地涂在碳纤维增强塑料(CFRP)表面的方法。获得了可热存储的CFRP,确定最大的放热和吸热量为30 J / g,其拉伸强度约为不含TPBD / CNF的CFRP的61%。

更新日期:2020-07-06
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