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Investigation on synthesis, laser damage threshold, and NLO properties of l -asparagine thioacetamide single crystal for photonic device applications
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-07-06 , DOI: 10.1007/s10854-020-03884-9
T. Suresh , S. Vetrivel , S. Gopinath , E. Vinoth

The optically colorless l-asparagine thioacetamide (LATA) single crystal was grown by the slow evaporation method at room temperature with water as a solvent. The lattice parameters of the grown crystal have been analyzed by the single crystal X-ray diffraction and it belongs to orthorhombic system with space group P212121. The crystalline nature of the title material was confirmed by powder XRD analysis. The functional groups were confirmed by using FT-IR spectral analysis. The grown crystal has a UV cut-off wavelength at 236 nm and various optical parameters were analyzed theoretically by using UV–Visible transmittance data. The enhancement of second harmonic generation efficiency of LATA crystal was found to be 2.4 times higher than that of standard KDP. The laser damage threshold of LATA crystal is determined as 13.47 J/cm2 by using Nd–YAG laser operated at 1064 nm. In the photoluminescence spectrum, the sharp emission peak was noticed at 470 nm which implies the blue emission. The grown crystal shows the positive photoconductive nature. The fluctuation of dielectric permittivity (Ɛo) and dielectric loss (tan δ) were analyzed at different temperatures as a function of frequency. The grown crystal was thermally stable up to 110.38 °C and it was assessed by (TG/DTA) analysis. The Vickers microhardness test was accomplished to identify the mechanical stability of the grown crystal. Hence, LATA crystal is the most suitable material for the optoelectronic device applications.



中文翻译:

用于光子器件的1-天冬酰胺硫代乙酰胺单晶的合成,激光损伤阈值和NLO性质的研究

通过缓慢蒸发法在室温下以水为溶剂生长光学无色的1-天冬酰胺硫代乙酰胺(LATA)单晶。通过单晶X射线衍射分析了生长晶体的晶格参数,该晶体属于空间群为P2 1 2 1 2 1的正交晶系。。通过粉末XRD分析确认标题材料的结晶性质。通过使用FT-IR光谱分析确认官能团。生长的晶体在236 nm处具有UV截止波长,并且通过使用UV-可见光透射率数据从理论上分析了各种光学参数。发现LATA晶体的二次谐波产生效率的增强是标准KDP的2.4倍。通过使用在1064 nm下工作的Nd-YAG激光,可确定LATA晶体的激光损伤阈值为13.47 J / cm 2。在光致发光光谱中,在470nm处观察到尖锐的发射峰,这暗示着蓝色发射。生长的晶体显示出正的光电导性质。介电常数(的变动ɛ Ô)和介电损耗(tanδ  δ)在不同温度下作为频率的函数进行分析。生长的晶体在高达110.38°C的温度下具有热稳定性,并通过(TG / DTA)分析对其进行了评估。完成维氏显微硬度测试以鉴定生长晶体的机械稳定性。因此,LATA晶体是最适合光电器件应用的材料。

更新日期:2020-07-06
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