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Templated grain growth of high coercive field CuO‐doped textured PYN‐PMN‐PT ceramics
Journal of the American Ceramic Society ( IF 3.9 ) Pub Date : 2020-07-04 , DOI: 10.1111/jace.17349
Michael J. Brova 1 , Beecher H. Watson 1 , Rebecca L. Walton 1 , Elizabeth R. Kupp 1 , Mark A. Fanton 2 , Richard J. Meyer 2 , Gary L. Messing 1
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This paper explores the templated grain growth and texturing of Pb(Yb1/2Nb1/2)O3‐Pb(Mg1/3Nb2/3)O3‐PbTiO3 (PYN‐PMN‐PT) ceramics. A PbO‐CuO liquid phase was determined to substantially increase the growth of PYN‐PMN‐PT on barium titanate template particles. Texturing resulted in an 83% enhancement in strain behavior (754 pm/V) compared with random PYN‐PMN‐PT ceramics (413 pm/V). The increased Pb(Yb1/2Nb1/2)O3 (PYN) content of textured 21PYN‐41PMN‐38PT resulted in a high coercive field of 13.9 kV/cm. Residual barium titanate templates reduced the polarization from 33.7 to 26.2 µC/cm2 and slightly decreased the Curie temperature (236‐224°C). These results show that textured PYN‐PMN‐PT is a promising material for high strain and coercive field transducers.

中文翻译:

高矫顽力的CuO掺杂质感PYN-PMN-PT陶瓷的模板化晶粒生长

本文探讨了Pb(Yb 1/2 Nb 1/2)O 3 -Pb(Mg 1/3 Nb 2/3)O 3 -PbTiO 3(PYN-PMN-PT)陶瓷的模板化晶粒生长和织构化。确定了PbO-CuO液相可显着增加PYN-PMN-PT在钛酸钡模板颗粒上的生长。与随机PYN-PMN-PT陶瓷(413 pm / V)相比,纹理化可将应变性能(754 pm / V)提高83%。织构化的21PYN-41PMN-38PT的Pb(Yb 1/2 Nb 1/2)O 3(PYN)含量增加,导致高矫顽场为13.9 kV / cm。残留的钛酸钡模板将极化从33.7降低至26.2 µC / cm2并稍微降低居里温度(236-224°C)。这些结果表明,带纹理的PYN-PMN-PT是用于高应变和矫顽场传感器的有前途的材料。
更新日期:2020-07-04
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