New ferrocenyl-containing Schiff bases Fc-CH=N-(5-CH₃-C₆H₃-OH) (1), Fc-CH=N-(4-Cl–C₆H₃–OH) (2) and Fc-CH=N-(4-CH₃-C₆H₃-OH) (3) have been synthesized by the condensation method. The molecular structures of 1–3 in crystal state were determined by single-crystal X-ray analysis. o-Iminophenols 1 and 3 crystallize in 1D chain motif, while o-iminophenol 2 form pairs due to the intermolecular hydrogen bonding. The interaction of o-iminophenols 1–3 with nickel(II) chloride in the presence of a base or with copper(II) acetate leads to new bis-o-iminophenolato complexes of the type (Fc-CH=N-(R-C₆H₃-O))₂M^II, where M = Ni, R = 5-Me (4), R = 4-Cl (5), R = 4-Me (6); M = Cu, R = 5-Me (7), R = 4-Cl (8), R = 4-Me (9). New compounds have been characterized by means of IR-spectroscopy, EI mass-spectrometry (4–9), elemental analysis, ¹H, ¹³C NMR-spectroscopy (for 1–6) and EPR-spectroscopy (for 7 and 8).

新的含二茂铁基席夫碱Fc-CH = N-（5-CH ₃ -C ₆ H ₃ -OH）（1），Fc-CH = N-（4-Cl–C ₆ H ₃ -OH）（2）通过缩合法合成了Fc-CH ＝ N-（4-CH ₃ -C ₆ H ₃ -OH）（3）。的分子结构1 - 3在结晶状态是由单晶X射线分析测定。邻亚氨基苯酚1和3以一维链基序结晶，而邻亚氨基苯酚2由于分子间氢键而形成对。在碱存在下，邻亚氨基苯酚1-3与氯化镍（II）或与乙酸铜（II）的相互作用导致生成新的双（-CH-N =（RC _6）邻氨基亚氨基酚络合物H ₃ -O））₂ M ^II，其中M = Ni，R = 5-Me（4），R = 4-Cl（5），R = 4-Me（6）；M ＝ Cu，R ＝ 5-Me（7），R ＝ 4-Cl（8），R ＝ 4-Me（9）。通过红外光谱，EI质谱（4 – 9），元素分析，¹ H，¹³ C NMR光谱（适用于1-6）和EPR光谱（适用于7和8）。