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A high-performance supercapacitor based on cerium molybdate nanoparticles anchored on N, P co-doped reduced graphene oxide nanocomposite as the electrode
Journal of Materials Science: Materials in Electronics ( IF 2.8 ) Pub Date : 2020-07-05 , DOI: 10.1007/s10854-020-03855-0
Abdollah Yari , Sajad Heidari Fathabad

Here, cerium (IV) molybdate nanoparticles (CeMo2O8) are anchored on the surface of an N, P co-doped reduced graphene oxide nanocomposite by a stepwise sonochemical approach and further investigated as an electrode for supercapacitors. The cerium (IV) molybdate/N, P co-doped reduced graphene oxide symmetric electrode exhibits an outstanding specific capacitance of 638 F g−1 at 2 mV s−1. The prominent electrochemical capacitive properties of nanocomposite electrode are attributed to the merits of high electrically conductive N, P co-doped reduced graphene oxide and short ion transport channels provided by CeMo2O8 nanoparticles together with the synergistic effect between the two combinations. Furthermore, the symmetric supercapacitor based on CeMo2O8/N, P co-doped reduced graphene oxide electrodes demonstrates a high energy density (29.7 W h kg−1 at 500 W kg−1), good power density (16,000 W kg−1 at 14.3 W h kg−1), and remarkable cycling stability (102.9% capacitance retention after 4000 cycles at 100 mV s−1). The results clearly show that co-doping small amounts of N and P onto the reduced graphene oxide, through a simple impregnating method, significantly improves the supercapacitive performance of the nanocomposite electrode.



中文翻译:

一种基于钼酸铈纳米粒子的高性能超级电容器,该纳米电容器锚固在N,P共掺杂的还原氧化石墨烯纳米复合材料上作为电极

在此,通过逐步声化学方法将钼酸铈(IV)纳米颗粒(CeMo 2 O 8)锚定在N,P共掺杂的还原型氧化石墨烯纳米复合材料的表面上,并进一步研究其作为超级电容器的电极。钼酸铈(IV)/ N,P共掺杂的还原氧化石墨烯对称电极在2 mV s -1下具有638 F g -1的出色比电容。纳米复合电极的突出的电化学电容特性归因于高导电性的N,P共掺杂的还原氧化石墨烯氧化物以及CeMo 2 O 8提供的短离子传输通道纳米颗粒以及两种组合之间的协同作用。此外,基于CEMO对称超电容器2 ö 8 / N,P共掺杂的还原氧化石墨烯电极演示了一个高能量密度(29.7 W时千克-1在500瓦千克-1),良好的功率密度(16,000千克w ^ - 1在14.3 W时千克-1),和显着的循环稳定性(在100mV小号4000次循环后102.9%容量保持-1)。结果清楚地表明,通过一种简单的浸渍方法,将少量的N和P共掺杂到还原的氧化石墨烯上,可以显着改善纳米复合电极的超电容性能。

更新日期:2020-07-05
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