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Use of thermal treatment with CaCl2 and CaO to remove 137Cs in the soil collected from the area near the Fukushima Daiichi Nuclear Power Plant.
Journal of Hazardous Materials ( IF 12.2 ) Pub Date : 2020-07-03 , DOI: 10.1016/j.jhazmat.2020.123364
Facun Jiao 1 , Norikazu Kinoshita 2 , Masato Kawaguchi 2 , Motoyuki Asada 2 , Maki Honda 3 , Keisuke Sueki 4 , Kenji Koido 5 , Yoshihiko Ninomiya 6
Affiliation  

A massive amount of soils and inflammable materials of plants etc. contaminated by radiocesium are generated from decontamination work in the Fukushima Daiichi Nuclear Power Plant (FDNPP) accident affected area. In present study, the removal experiments of 137Cs in a soil collected from the FDNPP accident affected area were carried out in a lab-scale electrical heating horizontal furnace through thermal treatment with CaCl2 addition over a temperature of 900 – 1300 °C. The results indicated that the average radioactive concentration of 137Cs in the soil was 52.8 Bq/g. The removal ratio of 137Cs in the soil treated at 1300 °C was 96.3% when 20% CaCl2 was added. The addition of CaCl2 and CaO mixture exhibited a synergistic effect on the removal of 137Cs, relative to the addition of CaCl2 alone. Accordingly, the addition of CaCl2 or its mixture with CaO during thermal treatment is suggested to remove 137Cs in the soil collected from the FDNPP accident affected area. Additionally, segregation of the soil sample to fine and coarse fraction and then treated individually are also recommended.



中文翻译:

使用CaCl2和CaO进行热处理,以去除从福岛第一核电站附近地区收集的土壤中的137Cs。

福岛第一核电站事故受灾地区的净化工作产生了大量被放射性铯污染的土壤和植物等易燃材料。在本研究中,从FDNPP事故影响地区收集的土壤中137 Cs的去除实验是在实验室规模的电加热卧式炉中进行的,该炉在900 – 1300°C的温度下添加CaCl 2进行热处理。结果表明,土壤中137 Cs的平均放射性浓度为52.8 Bq / g。添加20%CaCl 2时,在1300°C处理的土壤中137 Cs的去除率为96.3%。CaCl 2的添加相对于单独添加CaCl 2,CaO混合物对137 Cs的去除具有协同作用。因此,建议在热处理过程中添加CaCl 2或其与CaO的混合物以去除从FDNPP事故影响区域收集的土壤中的137 Cs。此外,还建议将土壤样品分离成细颗粒和粗颗粒,然后分别处理。

更新日期:2020-07-03
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