A transition‐metal‐free cross‐coupling of arylsilanes with DAST (diethylaminosulfur trifluoride) reagent has been developed. A number of aromatic sulfinamides were obtained in reasonable yields (15%‐87%). Notable advantages of this method include easy operation, mild reaction conditions and wide substrate scope.

中文翻译：

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芳基硅烷与DAST试剂的无过渡金属交叉偶联：芳香亚磺酰胺的合成

已经开发了一种无过渡金属的芳基硅烷与DAST（二乙基氨基三氟化硫）试剂的交叉偶联方法。以合理的产率（15％-87％）获得了许多芳香亚磺酰胺。该方法的显着优点包括操作简便，反应条件温和和底物范围广。