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Cover Feature: Enantiomerically Pure Tetravalent Neptunium Amidinates: Synthesis and Characterization (Chem. Eur. J. 41/2020)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-07-02 , DOI: 10.1002/chem.202003032
Sebastian Fichter 1 , Sebastian Kaufmann 2 , Peter Kaden 1 , Tobias S. Brunner 2 , Thorsten Stumpf 1 , Peter W. Roesky 2 , Juliane März 1
Affiliation  

Enantiomerically pure tetravalent neptunium amidinate complexes possessing unprecedented neptunium–halide bonds have been prepared by salt metathesis and subsequent (pseudo)halide exchange reactions. Structural characterization in solid state (SC‐XRD) and in solution (NMR) showed the preservation of the chirality‐at‐metal throughout the series of heteroleptic fluoro, chloro, bromo, and azido complexes. More information can be found in the Communication by J. März et al. on page 8867.
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中文翻译:

封面人物:对映体纯的四价mid酰胺盐:合成与表征(化学Eur。J. 41/2020)

通过盐复分解和随后的(伪)卤化物交换反应,已经制备了具有空前的n-卤键的对映体纯的四价a酰胺络合物。固态(SC-XRD)和溶液(NMR)的结构表征表明,在一系列杂合的氟,氯,溴和叠氮基络合物中,金属的手性得以保留。有关更多信息,请参见J.März等的《通讯》。在第8867页。
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更新日期:2020-07-20
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