当前位置: X-MOL 学术Chem. Commun. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
A tropylium annulated N-heterocyclic carbene.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-07-01 , DOI: 10.1039/d0cc04482b
Sebastian Appel 1 , Peter Brüggemann , Christian Ganter
Affiliation  

Derivatives of the cationic tropylium annulated imidazolylidene ITrop+ are obtained by hydride abstraction from related cycloheptatriene compounds. Spectroscopic, structural and theoretical data indicate that, as a cationic relative of benzimidazolylidenes, ITrop+ has highly reduced σ-donor and strong π-acceptor character.

中文翻译:

yl鎓环化的N-杂环卡宾。

通过氢化物从相关的环庚三烯化合物中提取氢化物,可以得到阳离子对苯二甲酰基咪唑基亚烷基ITrop +的衍生物。光谱,结构和理论数据表明,ITrop +作为苯并咪唑基亚胺的阳离子亲和性,具有高度还原的σ供体和强的π受体特性。
更新日期:2020-08-06
down
wechat
bug