Electron transfer induced self-assembly of a molecular tweezer platform.,Chemistry - A European Journal

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Electron transfer induced self-assembly of a molecular tweezer platform.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-06-30 , DOI: 10.1002/chem.202001919
Khushabu Thakur ₁ , Denan Wang ₁ , Saber Mirzaei ₁ , Rajendra Rathore ₁

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The design and synthesis of a new molecular tweezer (T‐tmp) with electron‐rich pincers are reported. The stable monocationic radicals and self‐assembled dimeric radicals of this molecular tweezer platform were prepared by chemical oxidative titration. With the aid of DFT calculations, it was found that the dimeric radicals with syn‐syn‐syn conformer has the most stable structure, with the hole primarily delocalized between parallel stacked pyrenyl groups.

中文翻译：

电子转移诱导分子钳平台的自组装。

报道了一种新型电子镊子（T-tmp）的设计和合成。通过化学氧化滴定法制备了该分子镊平台的稳定的单阳离子自由基和自组装的二聚自由基。借助DFT计算，发现具有syn – syn – syn构象异构体的二聚基团具有最稳定的结构，其中的空穴主要在平行堆积的enyl烯基之间散布。

更新日期：2020-06-30

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