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Preparation of visible light-responsive photocatalytic paper containing BiVO4@diatomite/MCC/PVBCFs for degradation of organic pollutants.
Ecotoxicology and Environmental Safety ( IF 6.2 ) Pub Date : 2020-07-01 , DOI: 10.1016/j.ecoenv.2020.110897
Chengliang Hua 1 , Xiangyao Liu 2 , Shixue Ren 1 , Caiwei Zhang 1 , Wenbo Liu 3
Affiliation  

Combining adsorption and photocatalysis is an effective strategy for degrading organic pollutants. Here, BiVO4@diatomite composite photocatalyst (BiVO4@diatomite CP) was prepared by hydrothermal synthesis from Bi(NO3)3·5H2O glycerin solution, NH4VO3 solution and diatomite. BiVO4@diatomite/microcrystalline cellulose/PVB composite fibers (BiVO4@diatomite/MCC/PVBCFs) were prepared from BiVO4@diatomite CPs, microcrystalline cellulose (MCC) and PVB ethanol solution using the electrospinning method. BiVO4@diatomite/MCC/PVBCFs were then mixed with pulp fibers to prepare the visible light-responsive photocatalytic paper. BiVO4@diatomite CP with a BiVO4/diatomite ratio of 6:4 had good interface states and displayed good photocatalytic activity with 64.32% degradation of methylene blue (MB) after 4 h. A PVB ethanol solution (6%) was formulated with BiVO4@diatomite CP and MCC to provide an ethanol spinning solution (12% solid) to prepare BiVO4@diatomite/MCC/PVBCFs (3:3:4). The resulting fibers had smooth surfaces, compact structures and exhibited good photocatalytic activity (66.80% and 56.80% degradation of MB and formaldehyde (HCHO), respectively, after 4 h). Photocatalytic paper containing 18% BiVO4@diatomite/MCC/PVBCFs had good photocatalytic activity with 50.20% degradation of HCHO after 4 h. This paper also had good physical properties and has the potential to be used for the photocatalytic degradation of indoor air pollutants, such as HCHO.



中文翻译:

制备含有BiVO4 @硅藻土/ MCC / PVBCF的可见光响应型光催化纸,用于降解有机污染物。

吸附和光催化相结合是降解有机污染物的有效策略。在此,通过水热合成由Bi(NO 33 ·5H 2 O甘油溶液,NH 4 VO 3溶液和硅藻土制备BiVO 4硅藻土复合光催化剂(BiVO 4硅藻土CP)。用静电纺丝法由BiVO 4硅藻土CP,微晶纤维素(MCC)和PVB乙醇溶液制备BiVO 4硅藻土/微晶纤维素/ PVB复合纤维(BiVO 4硅藻土/ MCC / PVBCF)。BiVO 4然后将硅藻土/ MCC / PVBCF与纸浆纤维混合以制备可见光响应性光催化纸。BiVO 4 /硅藻土比为6:4的BiVO 4硅藻土CP具有良好的界面态,并显示出良好的光催化活性,4 h后亚甲基蓝(MB)降解64.32%。用BiVO 4硅藻土CP和MCC配制PVB乙醇溶液(6%)以提供乙醇纺丝溶液(12%固体)以制备BiVO 4硅藻土/ MCC / PVBCF(3:3:4)。所得纤维具有光滑的表面,致密的结构并表现出良好的光催化活性(4小时后MB和甲醛(HCHO)的降解分别为66.80%和56.80%)。含18%BiVO 4的光催化纸硅藻土/ MCC / PVBCFs具有良好的光催化活性,4 h后HCHO降解50.20%。该纸还具有良好的物理性能,并具有用于光催化降解室内空气污染物(例如HCHO)的潜力。

更新日期:2020-07-01
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