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Studies on polyoxyethylene octyl phenyl ether supported thorium(IV) phosphates: a new cation exchange material
Bulletin of Materials Science ( IF 1.9 ) Pub Date : 2020-07-01 , DOI: 10.1007/s12034-020-02153-z
AMITA SOMYA , KALPANA MAHERIA

A new surfactant supported cation exchanger and adsorbent named, polyoxyethylene octyl phenyl ether supported thorium(IV) phosphate (TX-100ThP) has been reported along with its synthesis, physico-chemical characterization such as scanning electron microscopy, X-ray diffraction, thermogravimetric analysis–differential thermal analysis and Fourier transform infra-red study. Following the characterization, the formed product has been tested for its efficiency in ion exchange chemistry and in analytical chemistry. For the testing, adsorption of alkaline earths—Mg 2+ , Ca 2+ , Sr 2+ and Ba 2+ and transition metal ions such as Fe 3+ , Mn 2+ , Ni 2+ , Cd 2+ , Co 2+ , Cu 2+ , Hg 2+ and Pb 2+ have been explored in different acidic media and the results revealed the selectivity of synthesized material towards Hg 2+ ions. On that basis, the material has been used to treat the binary laboratory-made samples, exploring the environmental importance of the cation exchanger in material science.

中文翻译:

聚氧乙烯辛基苯基醚负载磷酸钍(IV)的研究:一种新型阳离子交换材料

已报道了一种新型表面活性剂负载的阳离子交换剂和吸附剂,名为聚氧乙烯辛基苯基醚负载的磷酸钍 (IV) (TX-100ThP) 及其合成、物理化学表征,如扫描电子显微镜、X 射线衍射、热重分析– 差热分析和傅里叶变换红外研究。在表征之后,已测试形成的产物在离子交换化学和分析化学中的效率。用于测试、吸附碱土金属——Mg 2+ 、Ca 2+ 、Sr 2+ 和Ba 2+ 以及过渡金属离子如Fe 3+ 、Mn 2+ 、Ni 2+ 、Cd 2+ 、Co 2+ 、 Cu 2+ 、Hg 2+ 和Pb 2+ 在不同的酸性介质中进行了探索,结果表明合成材料对Hg 2+ 离子的选择性。在此基础上,
更新日期:2020-07-01
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