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Effect of Agar as Electrolyte Additive on the Aluminum-Air Batteries
Journal of The Electrochemical Society ( IF 3.1 ) Pub Date : 2020-06-29 , DOI: 10.1149/1945-7111/ab9cc7
Woo-Hyuk Lee , Seok-Ryul Choi , Jung-Gu Kim

The performance of aluminum-air battery is improved by adding agar molecules to the electrolyte (4 M NaOH). A significant suppression of the parasitic self-corrosion reaction and the improvement of fuel efficiency were obtained. The fuel efficiency is elevated up to 35.95% and the corrosion inhibition efficiency increases up to 62.8%. The physisorption of the agar molecules on the aluminum surface improved the performance of aluminum-air battery. The adsorption of agar molecules on the aluminum surface was observed from the surface analysis with SEM, Freundlich adsorption isotherm and the adsorption energies from the computational simulations. Furthermore, the optimized structure model of agar molecules on the aluminum surface was proposed. To figure out the inhibition performance of agar molecules as an electrolyte additive for aluminum-air batteries, the experimental methods such as hydrogen evolution test, electrochemical tests, surface analysis and density functional theory ...

中文翻译:

琼脂作为电解质添加剂对铝空气电池的影响

通过将琼脂分子添加到电解质(4 M NaOH)中来改善铝空气电池的性能。显着抑制了寄生自腐蚀反应并提高了燃油效率。燃油效率提高到35.95%,缓蚀效率提高到62.8%。琼脂分子在铝表面的物理吸附改善了铝空气电池的性能。通过SEM,Freundlich吸附等温线和计算模拟的吸附能观察到琼脂分子在铝表面的吸附。此外,提出了铝表面琼脂分子的优化结构模型。
更新日期:2020-06-30
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