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Modifying the luminescent properties of a Cu(i) diphosphine complex using ligand-centered reactions in single crystals.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-06-30 , DOI: 10.1039/d0cc03427d
Kyounghoon Lee 1 , Po-Ni Lai 2 , Riffat Parveen 3 , Courtney M Donahue 1 , Mikayla M Wymore 1 , Blake A Massman 1 , Bess Vlaisavljevich 3 , Thomas S Teets 2 , Scott R Daly 1
Affiliation  

Here we report how reactions at a chemically reactive diphosphine shift the long-lived luminescent colour of a crystalline three-coordinate Cu(I) complex from green to blue. The results demonstrate how vapochromism and single-crystal-to-single-crystal transformations can be achieved using ligand-centered reactions.

中文翻译:

在单晶中使用以配体为中心的反应来修饰Cu(i)二膦配合物的发光性质。

在这里,我们报告在化学反应性二膦的反应如何将晶体三坐标Cu(I)配合物的长寿命发光颜色从绿色变为蓝色。结果表明使用配位体为中心的反应如何实现气相致变色和单晶至单晶转化。
更新日期:2020-08-11
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