当前位置：
X-MOL 学术
›
Acc. Chem. Res.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Water Adsorption in Soft and Heterogeneous Nanopores.
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2020-06-29 , DOI: 10.1021/acs.accounts.0c00215 François-Xavier Coudert 1
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2020-06-29 , DOI: 10.1021/acs.accounts.0c00215 François-Xavier Coudert 1
Affiliation
|
Liquids under confinement differ in behavior from their bulk counterparts and can acquire properties that are specific to the confined phase and linked to the nature and structure of the host matrix. While confined liquid water is not a new topic of research, the past few years have seen a series of intriguing novel features for water inside nanoscale pores. These unusual properties arise from the very specific nature of nanoporous materials, termed “soft porous crystals”; they combine large-scale flexibility with a heterogeneous internal surface. This creates a rich diversity of behavior for the adsorbed water, and the combination of different experimental characterization techniques along with computational chemistry at various scales is necessary to understand the phenomena observed and their microscopic origins. The range of systems of interest span the whole chemical range, from the inorganic (zeolites, imogolites) to the organic (microporous carbons, graphene, and its derivatives), and even encompass the hybrid organic–inorganic systems (such as metal–organic frameworks).
中文翻译：
软和非均质纳米孔中的水吸附。
受限制的液体的行为与其本体同类物不同，并且可以获取特定于限制相并与主体基质的性质和结构相关的特性。尽管封闭式液态水不是研究的新课题，但过去几年中，纳米级孔隙中的水具有一系列吸引人的新颖特征。这些不寻常的特性是由纳米多孔材料的非常特殊的性质引起的，被称为“软多孔晶体”。它们将大规模的灵活性与异质的内表面结合在一起。这为吸附的水创造了丰富的行为多样性，并且必须结合使用不同规模的不同实验表征技术和计算化学方法，才能理解所观察到的现象及其微观起源。
更新日期：2020-07-21
中文翻译：
软和非均质纳米孔中的水吸附。
受限制的液体的行为与其本体同类物不同，并且可以获取特定于限制相并与主体基质的性质和结构相关的特性。尽管封闭式液态水不是研究的新课题，但过去几年中，纳米级孔隙中的水具有一系列吸引人的新颖特征。这些不寻常的特性是由纳米多孔材料的非常特殊的性质引起的，被称为“软多孔晶体”。它们将大规模的灵活性与异质的内表面结合在一起。这为吸附的水创造了丰富的行为多样性，并且必须结合使用不同规模的不同实验表征技术和计算化学方法，才能理解所观察到的现象及其微观起源。
京公网安备 11010802027423号