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Production of hydrogen and multi-walled carbon nanotubes by ethanol decomposition over Fe/CeO2 catalysts
Energy Sources, Part A: Recovery, Utilization, and Environmental Effects ( IF 2.3 ) Pub Date : 2020-06-30 , DOI: 10.1080/15567036.2020.1786193
Yupeng Xiao 1 , Wenju Wang 1 , Tianle Li 1 , Chenglong Liu 1
Affiliation  

Fe/CeO2 catalysts with different ferrum loading were prepared by solid state melting method. Ethanol decomposition on those catalysts at different temperature (600, 700, and 800°C) has been studied. To evaluate the catalytic performance in ethanol decomposition, gaseous and solid products produced from ethanol decomposition were collected and analyzed; H2 and multi-walled carbon nanotubes (MWCNTs) were obtained. In these experiments, ethanol decomposition on Fe (30 wt%)/CeO2 at 600°C showed the maximum H2 yield (the maximum H2 yield was 94%, which was higher than that of previous reports). In addition, other gaseous products include CH4 and CO were observed, but CO2 was not be detected. The content of H2, CO, and CH4 were 60 ~ 80%, 20 ~ 25%, and 0 ~ 10%, respectively. MWCNTs have formed in ethanol decomposition process, the quality and purity of MWCNTs increase with increasing temperature, and the material with the carbon-encapsulated metal structure was obtained.



中文翻译:

Fe / CeO2催化剂上乙醇分解制氢和多壁碳纳米管

采用固态熔融法制备了不同铁负载量的Fe / CeO 2催化剂。研究了在不同温度(600、700和800°C)下这些催化剂上的乙醇分解。为了评估乙醇分解的催化性能,收集并分析了乙醇分解产生的气态和固态产物。获得了H 2和多壁碳纳米管(MWCNT)。在这些实验中,乙醇在600°C的Fe(30 wt%)/ CeO 2上分解显示出最大的H 2产率(最大H 2产率为94%,高于以前的报道)。另外,观察到其他气态产物包括CH 4和CO,但是CO 2未检测到。H 2,CO和CH 4的含量分别为60〜80%,20〜25%和0〜10%。在乙醇分解过程中形成了多壁碳纳米管,随着温度的升高,多壁碳纳米管的质量和纯度逐渐提高,得到了具有碳包封金属结构的材料。

更新日期:2020-06-30
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