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UV polymerization and property analysis of maleacylated methyl cellulose acrylic acid absorbent resin
Polish Journal of Chemical Technology ( IF 0.7 ) Pub Date : 2020-06-01 , DOI: 10.2478/pjct-2020-0014
Ying Li 1 , Amatjan Sawut 2 , Gongbo Hou , Mingyu He , Mamatjan Yimit
Affiliation  

Abstract In this paper, maleic anhydride (MA) was grafted onto methyl cellulose (MC) and then reacted with acrylic acid to synthesize a high gel strength and fast water absorption resin (AA-co-MC-g-MA) by UV polymerization. The reaction conditions of maleylated methylcellulose (MC-g-MA) were investigated, including the ratio of MC to MA, reaction time and catalyst amount. In addition, the reaction conditions for the synthesis of super absorbent resin were as follows: the amount of MC-g-MA, the degree of substitution of MC-g-MA, polymerization time, and the amount of initiator. Under optimal conditions, the maximum water absorption volume of synthetic resin was 2116 g/g, and the maximum salt absorption rate was 139 g/g. The water absorption resin prepared this time had high water absorption, water retention, excellent pH sensitivity, etc. It was hoped that it will have a good application prospect in the field of industrial production and agriculture in the future.

中文翻译:

马来酰化甲基纤维素丙烯酸吸水树脂的紫外聚合及性能分析

摘要 本文将马来酸酐(MA)接枝到甲基纤维素(MC)上,然后与丙烯酸反应,通过UV聚合合成了一种高凝胶强度和快速吸水的树脂(AA-co-MC-g-MA)。考察了马来酰化甲基纤维素(MC-g-MA)的反应条件,包括MC与MA的比例、反应时间和催化剂用量。此外,合成高吸水性树脂的反应条件为:MC-g-MA的用量、MC-g-MA的取代度、聚合时间和引发剂的用量。在优化条件下,合成树脂的最大吸水量为2116 g/g,最大吸盐率为139 g/g。本次制备的吸水树脂具有吸水率高、保水性好、pH敏感性优良等特点。
更新日期:2020-06-01
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