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Heteroarene-tethered Functionalized Alkyne Metamorphosis.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-06-30 , DOI: 10.1002/chem.202002154 Debojyoti Bag 1 , Sanghapal D Sawant 1
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-06-30 , DOI: 10.1002/chem.202002154 Debojyoti Bag 1 , Sanghapal D Sawant 1
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Heteroarene‐tethered functionalized alkynes are multipotent synthons in organic chemistry. This detailed Review described herein offers a thorough discussion of the metamorphosis of heteroarene‐tethered functionalized alkynes, an area which has earned much attention over the past decade in the straightforward synthesis of architecturally complex heterocyclic scaffolds in atom and step economic manner. Depending upon the variety of functionalized alkynes, this Review is divided into multiple sections. Amongst the vast array of synthetic transformations covered, dearomatizing spirocyclizations and cascade spirocyclization/rearrangement are of great interest. Synthetic transformations involving the heteroarene‐tethered functionalized alkynes with scope, challenges, limitations, mechanism, their application in the total synthesis of natural products and future perceptions are surveyed.
中文翻译：
杂芳烃系链的功能性炔烃变质。
杂芳烃系的官能化炔烃是有机化学中的多能合成子。本文所述的详细评论提供了杂芳烃系链的功能化炔烃的变态的详尽讨论，该领域在过去十年中以原子和阶梯经济方式直接合成结构复杂的杂环骨架备受关注。根据功能化炔烃的种类，本评论分为多个部分。在涵盖的众多合成转化中，脱芳香化的螺环化和级联的螺环化/重排非常令人感兴趣。涉及杂芳烃连接的官能化炔烃的合成转化，其范围，挑战，局限性，机理，
更新日期：2020-06-30
中文翻译：
杂芳烃系链的功能性炔烃变质。
杂芳烃系的官能化炔烃是有机化学中的多能合成子。本文所述的详细评论提供了杂芳烃系链的功能化炔烃的变态的详尽讨论，该领域在过去十年中以原子和阶梯经济方式直接合成结构复杂的杂环骨架备受关注。根据功能化炔烃的种类，本评论分为多个部分。在涵盖的众多合成转化中，脱芳香化的螺环化和级联的螺环化/重排非常令人感兴趣。涉及杂芳烃连接的官能化炔烃的合成转化，其范围，挑战，局限性，机理，
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