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Rapid synthesis of zirconolite ceramic wasteform by microwave sintering for disposition of plutonium
Journal of Nuclear Materials ( IF 2.8 ) Pub Date : 2020-06-30 , DOI: 10.1016/j.jnucmat.2020.152332
Zi-Jun Wei , Lewis R. Blackburn , Laura J. Gardner , Sheng-Heng Tan , Shi-Kuan Sun , Wei-Ming Guo , Neil C. Hyatt , Hua-Tay Lin

The application of microwave synthesis – sintering to the fabrication of zirconolite (CaZrTi2O7), as a candidate waste form for plutonium immobilization, was demonstrated as an alternative to conventional solid state reactive sintering. Ceramics of near-theoretical density were produced with a rapid dwell time of just 10 min at 1400 °C, and overall throughput time of just 60 min. In comparison with processing at 1200 °C, elevation of the processing temperature to 1400 °C significantly improved the microstructure homogeneity and reduced the porosity. The ability to sinter in air presents the potential advantage and allows for flexible control of redox conditions.



中文翻译:

微波烧结处理synthesis快速合成锆石陶瓷废料

微波合成烧结在锆石(CaZrTi 2 O 7)的制造中的应用已作为常规固相反应烧结的替代方法,作为z固定化的候选废料,已得到证明。接近理论密度的陶瓷在1400°C的快速停留时间仅为10分钟,总吞吐时间仅为60分钟。与在1200°C下进行处理相比,将处理温度提高到1400°C可以显着改善微观结构的均匀性并降低孔隙率。在空气中烧结的能力展现了潜在的优势,并允许灵活控制氧化还原条件。

更新日期:2020-06-30
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