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Oligomerization: An Inherent Property of Sulfonimidamides?
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-06-29 , DOI: 10.1002/ejoc.202000802
Yantao Chen 1 , Carl-Johan Aurell 2 , Rebecca Rae 1
Affiliation  

Deprotection of sulfonimidamides with formic acid in a long period of reaction time (hours to days) leads to the formation of the unexpected oligomeric sulfonimidamides. This work demonstrates that an unprotected sulfonimidamide can also undergo a similar oligomerization in a neutral solvent. The results show that oligomerization is an inherent property of sulfonimidamides.
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中文翻译:

齐聚:磺酰胺的固有性质?

在长时间的反应时间(数小时至数天)中,用磺酸对亚磺酰胺酰胺进行脱保护,导致形成意想不到的低聚亚磺酰胺。这项工作表明,未保护的磺酰亚胺酰胺也可以在中性溶剂中进行类似的低聚反应。结果表明,低聚是磺酰亚胺酰胺的固有性质。
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更新日期:2020-08-17
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