Front Cover: Dithieno[3,4‐b:3',4'‐d]arsole: A Novel Class of Hetero[5]radialenes (Eur. J. Org. Chem. 26/2020),European Journal of Organic Chemistry

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Front Cover: Dithieno[3,4‐b:3',4'‐d]arsole: A Novel Class of Hetero[5]radialenes (Eur. J. Org. Chem. 26/2020)
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-06-29 , DOI: 10.1002/ejoc.202000884
Aya Urushizaki ₁ , Takashi Yumura ₂ , Yuichi Kitagawa _{3,

4} , Yasuchika Hasegawa _{3,

4} , Hiroaki Imoto _{1,

5} , Kensuke Naka _{1,

5}

Affiliation

The Front Cover shows characteristic features of dithieno[3,4‐b :3',4'‐d ]arsole, which has been newly synthesized as a novel class of hetero[5]radialenes. It exhibited phosphorescence, while only fluorescence was observed for the isomer, dithieno[3,2‐b :2',3'‐d ]arsole. In addition, the arsa[5]radialene had high stability under ambient condition unlikely to hydrocarbon‐only [5]radialene because the Diels–Alder dimerization/polymerization was circumvented. More information can be found in the Full Paper by H. Imoto, K. Naka et al.

中文翻译：

封面：Dithieno [3,4-b：3'，4'-d] arsole：一类新的杂[5] radialenes（Eur。J. Org。Chem。26/2020）

封面显示了dithieno [3,4- b：3'，4'- d ] arsole的特征，该化合物是新合成的一类异[5] radialenes新化合物。它显示出磷光，而仅对异构体二硫杂[3,2- b：2'，3'- d ] arsole观察到荧光。此外，由于避开了Diels-Alder二聚/聚合反应，arsa [5]芳烃在环境条件下具有很高的稳定性，而仅含烃的[5]芳烃不太可能。可以在H. Imoto，K. Naka等人的论文全文中找到更多信息。

更新日期：2020-07-08

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