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Cover Feature: Visible Light‐Induced Radical Iodoperfluoroalkylation of Unactivated Olefins Cooperatively Catalyzed by Enamines and Amines (Eur. J. Org. Chem. 25/2020)
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2020-06-29 , DOI: 10.1002/ejoc.202000883
Tomoko Yajima 1 , Mao Murase 1 , Yu Ofuji 1
Affiliation  

The Cover Feature shows visible light induced radical perfluoroalkylation catalyzed by amine and enamine. Various unactivated alkenes and alkynes are reacted with perfluoroalkyl iodide to give corresponding iodopefluoroalkylation product in the presence of catalytic amount of diphenylacetaldehyde and pyrrolidine under photoirradiation using 23W CFL lamp. We thank Aya Nishikawa for drawing such a cute picture. More information can be found in the Communication by T. Yajima et al.
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中文翻译:

封面人物:烯胺和胺协同催化的未活化烯烃的可见光诱导自由基碘过氟烷基化反应(欧洲有机化学杂志,25/2020年)

覆盖特征显示了由胺和烯胺催化的可见光诱导的自由基全氟烷基化。在有催化量的二苯乙醛和吡咯烷的存在下,使用23W CFL灯在光催化条件下,使各种未活化的烯烃和炔烃与全氟烷基碘反应,生成相应的碘全氟烷基化产物。我们感谢西川A绘制如此可爱的图画。有关更多信息,请参见T. Yajima等人在《通讯》中的内容。
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更新日期:2020-07-01
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