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Construction of CdIn2O4/In2O3 composites containing n-n heterojunctions with excellent nitro-alkanes sensing performance
Materials Today Communications ( IF 3.7 ) Pub Date : 2020-06-29 , DOI: 10.1016/j.mtcomm.2020.101405
Yingjuan Wei , Guanjun Pan , Yi He

Developing a technique for the detection of nitro-alkanes, which are explosive and toxic, is vital. However, it is hard to selectively detect these compounds at low concentrations for early leakage warning. Here, a nanocomposite material was prepared to promote electron transfer and enhance the content of chemically absorbed oxygen by creating an n-n heterojunction between CdIn2O4 and In2O3, leading to an enhanced response, shortened response time and reduced working temperature. As a result, the best sensor was found to exhibit an ultra-high response of 78 to 10 ppm nitropropane with quite a low detection limit of 50 ppb at 100 °C. Furthermore, the designed sensor was nearly insensitive to ethanol, acetone, hydrogen, CO, methanol, toluene and methane. Presently, the sensor demonstrated the highest response among those studied in previous investigations.



中文翻译:

含nn异质结的CdIn 2 O 4 / In 2 O 3复合材料的构建,具有优异的硝基烷感测性能

开发一种爆炸性和有毒的硝基烷烃检测技术至关重要。但是,很难有选择地检测低浓度的这些化合物以进行早期泄漏预警。此处,制备了纳米复合材料,以通过在CdIn 2 O 4和In 2 O 3之间形成nn异质结来促进电子转移并提高化学吸收的氧含量。,从而提高响应速度,缩短响应时间并降低工作温度。结果,发现最好的传感器表现出78至10 ppm硝基丙烷的超高响应,在100°C时的检测限仅为50 ppb。此外,设计的传感器对乙醇,丙酮,氢气,CO,甲醇,甲苯和甲烷几乎不敏感。目前,在先前的研究中,传感器表现出最高的响应。

更新日期:2020-06-29
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