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Effects of alumina on the thermal processing of apatite-wollastonite: changes in sintering, microstructure and crystallinity of compressed pellets
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-06-29 , DOI: 10.1016/j.jeurceramsoc.2020.06.071
Priscila Melo , Marcin Kotlarz , Martyn Marshall , Marlin Magallanes , Ana Marina Ferreira , Piergiorgio Gentile , Kenneth Dalgarno

In this work we investigated the sintering behaviour of apatite-wollastonite (AW) glass-ceramic powders with the presence of alumina, firstly detected as a potentially useful surface contaminant derived from the ball milling of the powder, and then as a dopant in the glass formulation. All powders were benchmarked against AW without alumina. A small percentage of contamination (0.14 wt%) showed to delay the melting of material, and lower densification derived from a lower ability to crystallize and higher stability in the glassy states. The doped AW revealed that an increase in alumina favoured the formation of a glassy phase, increasing the degree of necking and the development of crystals. In conclusion, the introduction of alumina improves the AW glass-ceramic processability when content and process parameters are optimized.



中文翻译:

氧化铝对磷灰石-硅灰石热处理的影响:烧结,压缩微丸的组织和结晶度的变化

在这项工作中,我们研究了有氧化铝存在的磷灰石-硅灰石(AW)玻璃陶瓷粉末的烧结行为,首先被检测为源自粉末球磨的潜在有用表面污染物,然后被检测为玻璃中的掺杂剂。公式。所有粉末均以不含氧化铝的AW为基准。少量的污染(0.14 wt%)显示出延迟了材料的熔化,并且较低的致密化源自较低的结晶能力和较高的玻璃态稳定性。掺杂的AW表明,氧化铝的增加有利于玻璃相的形成,增加了颈缩的程度和晶体的发展。总之,当优化含量和工艺参数时,氧化铝的引入改善了AW玻璃陶瓷的可加工性。

更新日期:2020-06-29
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