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Embedding Pt nanoparticles at the interface of CdS/NaNbO3 nanorods heterojunction with bridge design for superior Z-Scheme photocatalytic hydrogen evolution
Applied Catalysis B: Environment and Energy ( IF 20.2 ) Pub Date : 2020-06-29 , DOI: 10.1016/j.apcatb.2020.119290
Fengli Yang , Quan Zhang , Juhua Zhang , Lu Zhang , Mengting Cao , Wei-Lin Dai

The development of heterojunction photocatalysts is still limited by poor interfacial charge carriers separation efficiency. In this work, we have successfully designed CdS/Pt/N-NaNbO3 multilayer bridged nanostructure by embedding of Pt nanoparticles (NPs) into the interface between CdS quantum dots (CdS QDs) and perovskite N-doped NaNbO3. The Pt NPs not only play the role of bonding CdS QDs and NaNbO3, but also provide a motive force for the charge carriers transfer and enormously shorten the migration path. Apart from the efficient Z-scheme charge transmission path of the CdS/Pt/N-NaNbO3 nanorods, strong visible light absorption (400−800 nm) can also be tailored by N doping and introducing of Pt NPs, CdS QDs, demonstrated by the UV–vis. DRS measurement. As expected, the photocatalytic hydrogen evolution rate of 18 %CdS/2%Pt/N-NaNbO3 nanorods is 134 and 28 times higher than that of bare NaNbO3 nanorods and CdS QDs, respectively, under visible light (λ > 420 nm). This is the highest value so far reported among the NaNbO3-based photocatalysts. This study has important implications for photocatalytic hydrogen evolution and novel fabrication of NaNbO3-based materials.



中文翻译:

将Pt纳米颗粒嵌入CdS / NaNbO 3纳米棒异质结的界面处,并采用桥设计,以实现优异的Z方案光催化制氢

界面电荷载流子分离效率差仍然限制了异质结光催化剂的发展。在这项工作中,我们通过将Pt纳米颗粒(NPs)嵌入CdS量子点(CdS QDs)和钙钛矿N掺杂NaNbO 3之间的界面中,成功设计了CdS / Pt / N-NaNbO 3多层桥接纳米结构。Pt NPs不仅起CdS QDs与NaNbO 3的键合作用,而且为电荷载流子的迁移提供动力,极大地缩短了迁移路径。除了CdS / Pt / N-NaNbO 3的高效Z方案电荷传输路径纳米棒具有很强的可见光吸收(​​400-800 nm),也可以通过N掺杂和引入Pt NP,CdS QD来定制,这在UV-vis上得到了证明。DRS测量。不出所料,在可见光(λ> 420 nm)下,18%CdS / 2%Pt / N-NaNbO 3纳米棒的光催化氢释放速率分别比裸NaNbO 3纳米棒和CdS QD高134和28倍。。这是迄今为止基于NaNbO 3的光催化剂中最高的值。这项研究对光催化氢的释放和基于NaNbO 3的材料的新颖制造具有重要意义。

更新日期:2020-07-06
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