Cascade Reactions in Chain-Growth Polymerization,Macromolecules

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Cascade Reactions in Chain-Growth Polymerization
Macromolecules ( IF 5.1 ) Pub Date : 2020-06-26 , DOI: 10.1021/acs.macromol.0c00417
Jingsong Yuan ₁ , Wenqi Wang ₁ , Zefeng Zhou ₁ , Jia Niu ₁

Affiliation

While the design and implementation of cascade reactions in organic chemistry and enzymatic biosynthesis flourished in the past decades, cascade reactions in polymerization remain an emerging concept with exciting opportunities. Cascade polymerization techniques can be used to generate polymers in which unique structures and functionalities are incorporated in the backbone of polymers, making them powerful tools to address the ever-increasing demand for new materials with improved functionality and sustainability. This Perspective highlights existing strategies for chain-growth cascade polymerizations following radical, ionic, nucleophilic, and transition metal catalysis mechanisms, with a focus on the design principle and reaction mechanism. Collectively, recent work illustrates the considerable potential and predicts future developments of chain-growth cascade polymerization, an active research field at the intersection of polymer science and organic chemistry.

中文翻译：

链增长聚合中的级联反应

在过去的几十年中，尽管有机化学和酶促生物合成中级联反应的设计和实施日趋盛行，但聚合中的级联反应仍是一个新兴的概念，具有令人兴奋的机遇。级联聚合技术可用于生成在聚合物主链中结合了独特结构和功能的聚合物，从而使其成为强大的工具，可以满足对功能性和可持续性不断提高的新材料的不断增长的需求。本观点重点介绍了自由基，离子，亲核和过渡金属催化机理之后链增长级联聚合的现有策略，重点是设计原理和反应机理。总的来说，

更新日期：2020-07-28

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