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C-As Bond Formation Reactions for the Preparation of Organoarsenic(III) Compounds.
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2020-06-26 , DOI: 10.1002/asia.202000606 Wee Shan Tay 1 , Sumod A Pullarkat 1
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2020-06-26 , DOI: 10.1002/asia.202000606 Wee Shan Tay 1 , Sumod A Pullarkat 1
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Potential widespread applications of organoarsenic chemistry have been limited by the inherent lack of safe and effective As−C bond formation reactions. Several alternative reagents and methods have been developed in the last few decades to address the hazards and drawbacks associated with traditional arsenic synthetic strategies. Herein, this minireview summarizes the advances made in nucleophilic, electrophilic, radical and metal‐mediated As(III)−C bond formations while specifically highlighting the behavior of arsenic synthons with various well‐established reagents (eg. Grignard reagents, organolithium compounds, organometallic reagents, radical initiators and Lewis/Brønsted bases). Avenues for asymmetric synthesis are also discussed, as are recent advances in organoarsenic chemistry suggesting that arsines exhibit novel reactivities independent from that of other relatively more well explored Group V cogeners.
中文翻译：
C-As键形成反应用于制备有机砷（III）化合物。
由于固有缺乏安全有效的As-C键形成反应，有机砷化学的潜在广泛应用受到了限制。在过去的几十年中，已经开发了几种替代试剂和方法来解决与传统砷合成策略相关的危害和弊端。在此，本综述概述了亲核，亲电，自由基和金属介导的As（III）-C键形成方面的进展，同时特别强调了砷合成子与各种公认的试剂（例如格氏试剂，有机锂化合物，有机金属化合物）的行为。试剂，自由基引发剂和Lewis /Brønsted碱）。还讨论了非对称合成的途径，
更新日期：2020-08-18
中文翻译：
C-As键形成反应用于制备有机砷（III）化合物。
由于固有缺乏安全有效的As-C键形成反应，有机砷化学的潜在广泛应用受到了限制。在过去的几十年中，已经开发了几种替代试剂和方法来解决与传统砷合成策略相关的危害和弊端。在此，本综述概述了亲核，亲电，自由基和金属介导的As（III）-C键形成方面的进展，同时特别强调了砷合成子与各种公认的试剂（例如格氏试剂，有机锂化合物，有机金属化合物）的行为。试剂，自由基引发剂和Lewis /Brønsted碱）。还讨论了非对称合成的途径，
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