当前位置: X-MOL 学术Calphad › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Design of ESR slag for remelting 9CrMoCoB steel through experiments and thermodynamic calculations
Calphad ( IF 2.4 ) Pub Date : 2020-06-27 , DOI: 10.1016/j.calphad.2020.101782
Leizhen Peng , Zhouhua Jiang , Xin Geng

To control the chemically active boron (B) in 9CrMoCoB within a narrow target range, thermodynamic calculations using FactSage 7.2 and equilibrium reaction experiments were conducted between slag and steel. First, equilibrium reaction experiments between 9CrMoCoB and slag of 55%CaF2–20%CaO–3%MgO–22%Al2O3x%B2O3 (x ≤ 3) were conducted to supplement and optimize the Henrian activity coefficient γ (lgγ = A/T + C, where A and C are constants) of B2O3 in the solution phase of FToxid-OXYL in FactSage 7.2. Second, the equilibrium reactions between 9CrMoCoB steel and slag of 55%CaF2–20%CaO–3%MgO–22%Al2O3x%SiO2y%B2O3 (x ≤ 3, y ≤ 3) were calculated by using FactSage 7.2 to study the effects of B2O3, SiO2, and O2 in the atmosphere on the contents of B, Si, and O in steel. Then, equilibrium reaction experiments were conducted to validate the calculated results. Finally, suitable slag was designed, and electroslag remelting (ESR) experiments were conducted for verification. Results showed that A = −6582 and C = 0 in the Henrian activity coefficient equation were suitable to the slag of 55%CaF2–20%CaO–3%MgO–22%Al2O3x%SiO2y%B2O3 (x ≤ 3, y ≤ 3), and the appropriate slag for ESR remelting the 9CrMoCoB steel was 55%CaF2–20%CaO–3%MgO–22%Al2O3–1%SiO2–1%B2O3. The volume percent of O2 had a stronger influence on the Si content, compared with B content. The volume percent of O2 should be less than 0.05% to produce the qualified 9CrMoCoB ingot when using the designed proper slag.



中文翻译:

通过实验和热力学计算设计重熔9CrMoCoB钢的ESR渣

为了将9CrMoCoB中的化学活性硼(B)控制在狭窄的目标范围内,使用FactSage 7.2进行了热力学计算,并在炉渣和钢之间进行了平衡反应实验。首先,9CrMoCoB和氟化钙的55%的炉渣之间平衡反应实验2 -20%的CaO-3%的MgO-22%的Al 2 ö 3 - X%B 2 ø 3X  ≤3)进行了补充和优化Henrian活动系数γ(LG γ  B的= A / T + C,其中A和C是常数)2 ö 3在FactSage 7.2中的FToxid-OXYL溶液相中。第二,钢9CrMoCoB和氟化钙的55%的炉渣之间的平衡反应2 -20%的CaO-3%的MgO-22%的Al 2 ö 3 - X%的SiO 2 - ý%B 2 ø 3X  ≤3,ÿ  ≤3通过使用FactSage 7.2计算B 2 O 3,SiO 2和O 2的影响来计算大气中钢中B,Si和O的含量 然后,进行平衡反应实验以验证计算结果。最后,设计了合适的炉渣,并进行了电渣重熔(ESR)实验以进行验证。结果表明,Henrian活度系数方程中的A = −6582和C = 0适用于55%CaF 2 –20%CaO–3%MgO–22%Al 2 O 3x%SiO 2y%的炉渣乙2 ø 3X  ≤3,ÿ  ≤3),和用于ESR的重熔钢9CrMoCoB适当炉渣为55%的CaF 2 -20%的CaO-3%的MgO-22%的Al 2 ö3 –1%​​SiO 2 –1%​​B 2 O 3。与B含量相比,O 2的体积百分比对Si含量的影响更大。使用设计适当的炉渣时,O 2的体积百分比应小于0.05%,以生产合格的9CrMoCoB铸锭。

更新日期:2020-06-27
down
wechat
bug