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Synthesis and Herbicidal and Antioxidant Activity of a Series of Hetero- and Carbocyclic Derivatives of Monochloroacetic Acid
Russian Journal of Applied Chemistry ( IF 0.6 ) Pub Date : 2020-06-26 , DOI: 10.1134/s1070427220050122
E. A. Yakovenko , Yu. L. Baimurzina , G. Z. Raskil’dina , S. S. Zlotskii

Abstract

Monochloroacetic acid esters and amides containing carbo- and heterocycles and heterocyclic esters and amides derived from commercial aryloxyacetyl chlorides were synthesized. The structures of the compounds were confirmed by 1Н and 13С spectroscopy. The herbicidal activity of the substances was studied with respect to mono- and dicotyledonous plants. The relative antioxidant activity of the compounds was studied by recording the luminol-dependent chemiluminescence. The experimental data, on the whole, confirm that the development of herbicides containing acetal and gem-dichlorocyclopropane fragments is appropriate and promising.


中文翻译:

一系列一氯乙酸的杂环和碳环衍生物的合成及其除草和抗氧化活性

摘要

合成了含有碳和杂环的一氯乙酸酯和酰胺,以及衍生自商业芳氧基乙酰氯的杂环酯和酰胺。化合物的结构经证实1 Н和13 С光谱。研究了该物质对单子叶和双子叶植物的除草活性。通过记录鲁米诺依赖性化学发光来研究化合物的相对抗氧化活性。总体而言,实验数据证实,开发含有乙缩醛和双氯二氯环丙烷片段的除草剂是适当且有希望的。
更新日期:2020-06-26
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