The glass compositions 20BaO–xTiO₂–(80–x)P₂O₅ with (x = 5, 10, and 20%mol) were elaborated by the conventional quenching method. These vitreous materials show a constant content of the barium oxide while the Ti/P ratio varies. They are characterized by X-ray diffraction in order to ascertain their amorphous nature. Density measurements are performed using diethyl orthophthalate as a medium liquid. It was found that their density and molar volume increases and reduces with TiO₂ content, respectively. Raman spectroscopic analysis is employed to characterize their structural approach. This technique revealed the occurrence of various structural units of phosphate in the glass-matrix, primarily pyrophosphates, and metaphosphates. The optical absorption study of glasses confirmed the existence of Ti³⁺ ions in all the glassy samples, and it was found that the optical bandgap depends on the composition of the glass and reduces as the TiO₂ content increases. Glass-ceramics relatives to the glasses were obtained by performing heat treatments of the glasses. The crystallized phases are identified using X-ray diffraction (XRD). It was found that a glass-ceramic containing a ferroelectric BaTiO₃ phase is developed by transforming a glass composition (x = 20) to a crystalline phase. The electrical properties of the glass-ceramics are performed by impedance spectroscopy in the frequency range of 100 Hz to 1 MHz under various temperatures from 300 to 573 K. The glass-ceramic (GC) (x = 20) at room temperature has the highest dielectric constant ε_r = 51.6 and lower dielectric loss Tanδ = 0.005, and it was found that the glass-ceramics are mixed conductors with both ionic and electronic conductivities. The obtained results are discussed according to the chemical composition of these materials.

 用常规的淬火方法制备了玻璃成分20BaO– x TiO ₂ –（80– x）P ₂ O ₅（x = 5、10和20％mol）。这些玻璃态材料显示出恒定的氧化钡含量，而Ti / P比却变化。它们通过X射线衍射来表征，以确定其无定形性质。使用邻苯二甲酸二乙酯作为介质液体进行密度测量。发现它们的密度和摩尔体积随着TiO _2的增加和减少内容。拉曼光谱分析用于表征其结构方法。该技术揭示了玻璃基质中磷酸盐的各种结构单元的出现，主要是焦磷酸盐和偏磷酸盐。玻璃的光吸收研究证实了所有玻璃样中都存在Ti ³⁺离子，并且发现带隙取决于玻璃的组成，并且随着TiO ₂含量的增加而减小。通过对玻璃进行热处理而获得与玻璃的玻璃陶瓷亲戚。使用X射线衍射（XRD）识别结晶相。发现含有铁电性BaTiO ₃的玻璃陶瓷通过将玻璃组合物（x  = 20）转变为结晶相，可形成有机相。在300至573 K的各种温度下，通过阻抗谱在100 Hz至1 MHz的频率范围内执行玻璃陶瓷的电性能。室温下的玻璃陶瓷（GC）（x  = 20）最高介电常数_εr  = 51.6和较低的介电损耗Tanδ= 0.005，并且发现玻璃陶瓷是具有离子和电子电导率的混合导体。根据这些材料的化学组成讨论了获得的结果。